Water solubility, thermal characteristics and biodegradability of extruded starch acetate foams

Y. X. Xu, Y. Dzenis, M. A. Hanna

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

Starch based foams have been studied as replacements for non-degradable expanded polystyrene (EPS) as loose-fill packaging material because of starch's total degradation and low cost. However, starch's hydrophilicity, poor mechanical properties and dimensional stability limited their applications. Acetylated starch with a high degree of substitution (DS) is an alternative. Starch acetates with DS 1.11, 1.68, and 2.23 were extruded with either water or ethanol as solvents. The effects of DS and type of solvent on the starch acetate foam's water absorption index (WAI), water solubility index (WSI), thermal behavior (glass transition temperature [Tg], melting temperature [Tm], and thermal decomposition temperature), and biodegradability were investigated. There was a significant interaction (P < 0.05) between solvent type and DS on WAI and WSI of the foams. As DS increased from 1.11 to 2.23, WAI and WSI increased when ethanol was used as solvent and decreased when water was used as solvent. The Tg values of starch decreased with acetylation and with increasing DS, but increased with extrusion. Acetylation and extrusion increased the thermal stability of the foams. The rate of biodegradation of the foams decreased with increasing DS. The foams, extruded with ethanol, had higher degradation rates than those with water.

Original languageEnglish (US)
Pages (from-to)361-368
Number of pages8
JournalIndustrial Crops and Products
Volume21
Issue number3
DOIs
StatePublished - May 1 2005

Fingerprint

biodegradability
water solubility
foams
Solubility
Hot Temperature
acetates
starch
heat
Water
Starch
ethanol
acetylation
extrusion
Ethanol
Acetylation
dimensional stability
thermal degradation
degradation
glass transition temperature
water

Keywords

  • Biodegradability
  • Degree of substitution
  • Starch acetate foams
  • Thermal behavior

ASJC Scopus subject areas

  • Agronomy and Crop Science

Cite this

Water solubility, thermal characteristics and biodegradability of extruded starch acetate foams. / Xu, Y. X.; Dzenis, Y.; Hanna, M. A.

In: Industrial Crops and Products, Vol. 21, No. 3, 01.05.2005, p. 361-368.

Research output: Contribution to journalArticle

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