Viscoelastic and transport properties of hydrophilic-hydrophobic multiblock copolymers

Yanfang Fan, Chris J. Cornelius, James McGrath, Hae Seung Lee, Yu Chen

Research output: Contribution to journalConference article

Abstract

A benchmark commercial proton exchange membrane (PEM) is Nafion®, developed by DuPont Company. However, poor mechanical properties and the drastic decrease of proton conductivity at high temperature (>80°C) restricted its application under fuel cell operation conditions. Further, the high cost and the high methanol permeability spur the need of developing novel PEM materials. Recent research of McGrath group focused on the development of novel multiblock copolymers as one promising PEM through controlling the block lengths. Two series of multiblock copolymers have been synthesized based on the coupling reaction of a hexafluorobenzene(HFB) end capped unsulfonated poly(arylene ether sulfone) (BPS0) or fluorine terminated poly(arylene ether ketone) (6FK) hydrophobic oligomer and a phenoxide terminated disulfonated poly(arylene ether sulfone) (BPSH) hydrophilic oligomer.

Original languageEnglish (US)
JournalACS National Meeting Book of Abstracts
StatePublished - Dec 1 2010
Event239th ACS National Meeting and Exposition - San Francisco, CA, United States
Duration: Mar 21 2010Mar 25 2010

Fingerprint

Ether
Transport properties
Protons
Ethers
Ion exchange
Sulfones
Copolymers
Membranes
Oligomers
Proton conductivity
Fluorine
Ketones
Methanol
Fuel cells
Mechanical properties
Costs
Industry
Temperature
perfluorosulfonic acid
hexafluorobenzene

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Viscoelastic and transport properties of hydrophilic-hydrophobic multiblock copolymers. / Fan, Yanfang; Cornelius, Chris J.; McGrath, James; Lee, Hae Seung; Chen, Yu.

In: ACS National Meeting Book of Abstracts, 01.12.2010.

Research output: Contribution to journalConference article

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