Using slow-release permanganate candles to remediate PAH-contaminated water

Lindy Rauscher, Chainarong Sakulthaew, Steve Comfort

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Surface waters impacted by urban runoff in metropolitan areas are becoming increasingly contaminated with polycyclic aromatic hydrocarbons (PAHs). Slow-release oxidant candles (paraffin-KMnO4) are a relatively new technology being used to treat contaminated groundwater and could potentially be used to treat urban runoff. Given that these candles only release permanganate when submerged, the ephemeral nature of runoff events would influence when the permanganate is released for treating PAHs. Our objective was to determine if slow-release permanganate candles could be used to degrade and mineralize PAHs. Batch experiments quantified PAH degradation rates in the presence of the oxidant candles. Results showed most of the 16 PAHs tested were degraded within 2-4h. Using 14C-labled phenanthrene and benzo(a)pyrene, we demonstrated that the wax matrix of the candle initially adsorbs the PAH, but then releases the PAH back into solution as transformed, more water soluble products. While permanganate was unable to mineralize the PAHs (i.e., convert to CO2), we found that the permanganate-treated PAHs were much more biodegradable in soil microcosms. To test the concept of using candles to treat PAHs in multiple runoff events, we used a flow-through system where urban runoff water was pumped over a miniature candle in repetitive wet-dry, 24-h cycles. Results showed that the candle was robust in removing PAHs by repeatedly releasing permanganate and degrading the PAHs. These results provide proof-of-concept that permanganate candles could potentially provide a low-cost, low-maintenance approach to remediating PAH-contaminated water.

Original languageEnglish (US)
Pages (from-to)441-449
Number of pages9
JournalJournal of Hazardous Materials
Volume241-242
DOIs
StatePublished - Nov 30 2012

Fingerprint

Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
PAH
Water
Runoff
water
runoff
Oxidants
oxidant
permanganic acid
Waxes
urban system
Benzo(a)pyrene
Pyrene
Groundwater
phenanthrene
wax
Surface waters
pyrene
Paraffin

Keywords

  • Permanganate
  • Polycyclic aromatic hydrocarbons
  • Slow-release oxidants

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution
  • Health, Toxicology and Mutagenesis

Cite this

Using slow-release permanganate candles to remediate PAH-contaminated water. / Rauscher, Lindy; Sakulthaew, Chainarong; Comfort, Steve.

In: Journal of Hazardous Materials, Vol. 241-242, 30.11.2012, p. 441-449.

Research output: Contribution to journalArticle

Rauscher, Lindy ; Sakulthaew, Chainarong ; Comfort, Steve. / Using slow-release permanganate candles to remediate PAH-contaminated water. In: Journal of Hazardous Materials. 2012 ; Vol. 241-242. pp. 441-449.
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