Total synthesis of peroxyacarnoates A and D

Metal-mediated couplings as a convergent approach to polyunsaturated peroxides

Chunping Xu, Joseph M. Raible, Patrick H Dussault

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

(Chemical Equation Presented) The first syntheses of peroxyacarnoates A and D, members of a family of enyne-containing alkoxydioxanes, have been achieved on the basis of chemoselective ozonolysis within a polyunsaturated framework and Pd-mediated cross-couplings of a functionalized 1,2-dioxane.

Original languageEnglish (US)
Pages (from-to)2509-2511
Number of pages3
JournalOrganic Letters
Volume7
Issue number12
DOIs
StatePublished - Jun 9 2005

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cross coupling
Peroxides
peroxides
Metals
synthesis
metals
peroxyacarnoate A
1,4-dioxane
peroxyacarnoate D

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Total synthesis of peroxyacarnoates A and D : Metal-mediated couplings as a convergent approach to polyunsaturated peroxides. / Xu, Chunping; Raible, Joseph M.; Dussault, Patrick H.

In: Organic Letters, Vol. 7, No. 12, 09.06.2005, p. 2509-2511.

Research output: Contribution to journalArticle

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