Synthesis and conductivity of binaphthyl-based conjugated polymers

Research output: Contribution to journalConference article

4 Citations (Scopus)

Abstract

Binaphthylene-thiophene copolymer where the oligothiophene covalently bonded to 2,2′ - site of 1,1′-binaphthylene has been prepared by Negishi coupling between 2,2′-bis(2-thiophene)-1,1′-binaphthlene and 2,2′-bis(5-bromo-2-thiophene)-l,l′-binaphthlene, and characterized by NMR, IR spectra. The molecular weight is estimated by the integration of 1H-NMR. The conductivity is measured as 3 × 10-5 S/cm based on chemically doping with NOPF6 (doped ratio 1:1) and 2.2 × 10-5 S/cm based on electrochemical doping, respectively.

Original languageEnglish (US)
Pages (from-to)1507-1508
Number of pages2
JournalSynthetic Metals
Volume137
Issue number1-3
DOIs
StatePublished - Apr 4 2003
EventICSM 2002 - Shanghai, China
Duration: Jun 29 2002Jul 5 2002

Fingerprint

Thiophenes
Conjugated polymers
Thiophene
thiophenes
conductivity
polymers
synthesis
Doping (additives)
Nuclear magnetic resonance
nuclear magnetic resonance
molecular weight
copolymers
Copolymers
Molecular weight

Keywords

  • Conductive polymers
  • Coupling reactions
  • Electrochemical doping

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Synthesis and conductivity of binaphthyl-based conjugated polymers. / Li, Jun; Rajca, Andrzej; Rajca, Suchada.

In: Synthetic Metals, Vol. 137, No. 1-3, 04.04.2003, p. 1507-1508.

Research output: Contribution to journalConference article

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abstract = "Binaphthylene-thiophene copolymer where the oligothiophene covalently bonded to 2,2′ - site of 1,1′-binaphthylene has been prepared by Negishi coupling between 2,2′-bis(2-thiophene)-1,1′-binaphthlene and 2,2′-bis(5-bromo-2-thiophene)-l,l′-binaphthlene, and characterized by NMR, IR spectra. The molecular weight is estimated by the integration of 1H-NMR. The conductivity is measured as 3 × 10-5 S/cm based on chemically doping with NOPF6 (doped ratio 1:1) and 2.2 × 10-5 S/cm based on electrochemical doping, respectively.",
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AU - Li, Jun

AU - Rajca, Andrzej

AU - Rajca, Suchada

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N2 - Binaphthylene-thiophene copolymer where the oligothiophene covalently bonded to 2,2′ - site of 1,1′-binaphthylene has been prepared by Negishi coupling between 2,2′-bis(2-thiophene)-1,1′-binaphthlene and 2,2′-bis(5-bromo-2-thiophene)-l,l′-binaphthlene, and characterized by NMR, IR spectra. The molecular weight is estimated by the integration of 1H-NMR. The conductivity is measured as 3 × 10-5 S/cm based on chemically doping with NOPF6 (doped ratio 1:1) and 2.2 × 10-5 S/cm based on electrochemical doping, respectively.

AB - Binaphthylene-thiophene copolymer where the oligothiophene covalently bonded to 2,2′ - site of 1,1′-binaphthylene has been prepared by Negishi coupling between 2,2′-bis(2-thiophene)-1,1′-binaphthlene and 2,2′-bis(5-bromo-2-thiophene)-l,l′-binaphthlene, and characterized by NMR, IR spectra. The molecular weight is estimated by the integration of 1H-NMR. The conductivity is measured as 3 × 10-5 S/cm based on chemically doping with NOPF6 (doped ratio 1:1) and 2.2 × 10-5 S/cm based on electrochemical doping, respectively.

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