Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers

Jered C Garrison, Matthew J. Panzner, Paul D. Custer, D. Venkat Reddy, Peter L. Rinaldi, Claire A. Tessier, Wiley J. Youngs

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The reaction of 4-ethynyl-pyridine with tert-butyl lithium followed by its addition to (Me3tacn)RhCl3 affords the facial octahedral complex (Me3tacn)Rh(CCPy)3, condensation of which with the square planar complex cis-(DCPE)Pt(NO3)2 results in a self-assembled trigonal bipyramidal cage with Rh(iii) and Pt(ii) atoms occupying the vertices.

Original languageEnglish (US)
Pages (from-to)4644-4646
Number of pages3
JournalChemical Communications
Issue number44
DOIs
StatePublished - Nov 9 2006

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Platinum metals
Rhodium
Lithium
Pyridine
Condensation
Atoms
3,4-dichlorophenylethanolamine
pyridine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers. / Garrison, Jered C; Panzner, Matthew J.; Custer, Paul D.; Reddy, D. Venkat; Rinaldi, Peter L.; Tessier, Claire A.; Youngs, Wiley J.

In: Chemical Communications, No. 44, 09.11.2006, p. 4644-4646.

Research output: Contribution to journalArticle

Garrison, Jered C ; Panzner, Matthew J. ; Custer, Paul D. ; Reddy, D. Venkat ; Rinaldi, Peter L. ; Tessier, Claire A. ; Youngs, Wiley J. / Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers. In: Chemical Communications. 2006 ; No. 44. pp. 4644-4646.
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