Surface thermal stability of iron pyrite nanocrystals: Role of capping ligands

Baodong Mao, Qingfeng Dong, Christopher L. Exstrom, Jinsong Huang

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Iron pyrite (FeS2) is a promising photovoltaic absorber material with a high natural abundance and low cost, but surface defects and low photoresponse inhibit sunlight energy conversion. The surface stability of pyrite FeS2 nanocrystals synthesized in oleylamine (OLA) with trioctylphosphine oxide (TOPO) as an additional capping ligand was investigated using Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray diffraction. Tunable laser exposure during Raman spectroscopy measurement was developed for convenient and systematic evaluation of the stability of FeS 2 nanocrystals. The surface stability of 100-200 nm diameter cubic nanocrystals with long-chain (OLA, TOPO) or small-molecule (pyridine) capping ligands was evaluated after high-intensity laser exposure as well as after thermal annealing in air and N2. While increasing surface coverage with OLA and TOPO capping ligands provided additional protection against oxidation, FeS2 nanocrystals capped with pyridine showed good stability at temperatures up to 200 °C in air and 400 °C in N 2. These results provide greater understanding of the processing of nanocrystal-based iron pyrite thin films for photovoltaic applications.

Original languageEnglish (US)
Pages (from-to)361-366
Number of pages6
JournalThin Solid Films
Volume562
DOIs
StatePublished - Jul 1 2014

Fingerprint

surface stability
Pyrites
pyrites
Nanocrystals
nanocrystals
Thermodynamic stability
thermal stability
Ligands
iron
ligands
Pyridine
Oxides
oxides
Raman spectroscopy
pyridines
absorbers (materials)
Laser tuning
air
Surface defects
energy conversion

Keywords

  • Iron pyrite
  • Ligand exchange
  • Photovoltaic
  • Surface stability
  • Thin films

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Surface thermal stability of iron pyrite nanocrystals : Role of capping ligands. / Mao, Baodong; Dong, Qingfeng; Exstrom, Christopher L.; Huang, Jinsong.

In: Thin Solid Films, Vol. 562, 01.07.2014, p. 361-366.

Research output: Contribution to journalArticle

Mao, Baodong ; Dong, Qingfeng ; Exstrom, Christopher L. ; Huang, Jinsong. / Surface thermal stability of iron pyrite nanocrystals : Role of capping ligands. In: Thin Solid Films. 2014 ; Vol. 562. pp. 361-366.
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