19 NMR and Structural Evidence for Spin-State Modulation of Six-Coordinate Cobalt(II) in a Weak Field Porphyrin Ligand

Valeriy V. Smirnov, Eric K. Woller, Stephen DiMagno

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Abstract

The syntheses and characterization of [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphinato]cobalt, Co(F 8 TPP), and [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl) porphinato]cobalt, Co(F 28 TPP), are reported. Co(F 28 TPP)·2tol (tol = toluene) crystallizes in the monoclinic space group C2/c-C h (No. 15) with a = 22.1616(5) Å, b = 12.0274(3) Å, c = 19.9159(2) Å, β = 110.645(1)°, V = 4967.6(2) Å 3 , and Z = 4 {d calcd = 1.818 g/cm 3 ; μ a (Mo Kα) = 0.50 mm -1 }, and Co(F 28 TPP)·2THF crystallizes in the triclinic space group P1̄ (No. 2) with a = 11.0691(1) Å, b = 12.0451(1) Å, c = 12.9558(2) Å. α = 62.531(1)°, β = 69.544(1)°, γ = 76.181(1)°, V = 1429.71(3) Å 3 and Z = 1 {d calcd = 1.700 g/cm 3 ; μ a (Mo Kα) = 0.45 mm -1 }. A comparison of the X-ray crystal structure data from Co(F 28 TPP)·2tol and Co(F 28 TPP)·2THF indicates that the porphyrin core expands dramatically (0.08 Å) in the six-coordinate complex. Optical and 19 F NMR spectroscopic studies of Co(F 28 TPP) in the presence of added ligand demonstrate that spin-state modulation of the six-coordinate Co(II) center is facile. Partial population of the 4 E g state is accessed upon coordination of the cobalt center with THF σ-donor ligands, while six-coordinate complexes with 1-methylimidazole result in complete conversion to the high spin state, as evinced by 280 ppm downfield chemical shifts for the β-fluorine resonances in the 19 F NMR spectrum. Co(F 28 TPP) is the first example of a porphyrin which supports a high-spin cobalt ion.

Original languageEnglish (US)
Pages (from-to)4971-4978
Number of pages8
JournalInorganic Chemistry
Volume37
Issue number19
StatePublished - Dec 1 1998

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Porphyrins
Cobalt
porphyrins
cobalt
Nuclear magnetic resonance
Modulation
Ligands
modulation
nuclear magnetic resonance
ligands
Fluorine
Toluene
Chemical shift
fluorine
chemical equilibrium
toluene
Crystal structure
Ions
X rays
crystal structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

19 NMR and Structural Evidence for Spin-State Modulation of Six-Coordinate Cobalt(II) in a Weak Field Porphyrin Ligand . / Smirnov, Valeriy V.; Woller, Eric K.; DiMagno, Stephen.

In: Inorganic Chemistry, Vol. 37, No. 19, 01.12.1998, p. 4971-4978.

Research output: Contribution to journalArticle

Smirnov, Valeriy V. ; Woller, Eric K. ; DiMagno, Stephen. / 19 NMR and Structural Evidence for Spin-State Modulation of Six-Coordinate Cobalt(II) in a Weak Field Porphyrin Ligand In: Inorganic Chemistry. 1998 ; Vol. 37, No. 19. pp. 4971-4978.
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abstract = "The syntheses and characterization of [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphinato]cobalt, Co(F 8 TPP), and [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl) porphinato]cobalt, Co(F 28 TPP), are reported. Co(F 28 TPP)·2tol (tol = toluene) crystallizes in the monoclinic space group C2/c-C h (No. 15) with a = 22.1616(5) {\AA}, b = 12.0274(3) {\AA}, c = 19.9159(2) {\AA}, β = 110.645(1)°, V = 4967.6(2) {\AA} 3 , and Z = 4 {d calcd = 1.818 g/cm 3 ; μ a (Mo Kα) = 0.50 mm -1 }, and Co(F 28 TPP)·2THF crystallizes in the triclinic space group P1̄ (No. 2) with a = 11.0691(1) {\AA}, b = 12.0451(1) {\AA}, c = 12.9558(2) {\AA}. α = 62.531(1)°, β = 69.544(1)°, γ = 76.181(1)°, V = 1429.71(3) {\AA} 3 and Z = 1 {d calcd = 1.700 g/cm 3 ; μ a (Mo Kα) = 0.45 mm -1 }. A comparison of the X-ray crystal structure data from Co(F 28 TPP)·2tol and Co(F 28 TPP)·2THF indicates that the porphyrin core expands dramatically (0.08 {\AA}) in the six-coordinate complex. Optical and 19 F NMR spectroscopic studies of Co(F 28 TPP) in the presence of added ligand demonstrate that spin-state modulation of the six-coordinate Co(II) center is facile. Partial population of the 4 E g state is accessed upon coordination of the cobalt center with THF σ-donor ligands, while six-coordinate complexes with 1-methylimidazole result in complete conversion to the high spin state, as evinced by 280 ppm downfield chemical shifts for the β-fluorine resonances in the 19 F NMR spectrum. Co(F 28 TPP) is the first example of a porphyrin which supports a high-spin cobalt ion.",
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AU - Smirnov, Valeriy V.

AU - Woller, Eric K.

AU - DiMagno, Stephen

PY - 1998/12/1

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N2 - The syntheses and characterization of [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphinato]cobalt, Co(F 8 TPP), and [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl) porphinato]cobalt, Co(F 28 TPP), are reported. Co(F 28 TPP)·2tol (tol = toluene) crystallizes in the monoclinic space group C2/c-C h (No. 15) with a = 22.1616(5) Å, b = 12.0274(3) Å, c = 19.9159(2) Å, β = 110.645(1)°, V = 4967.6(2) Å 3 , and Z = 4 {d calcd = 1.818 g/cm 3 ; μ a (Mo Kα) = 0.50 mm -1 }, and Co(F 28 TPP)·2THF crystallizes in the triclinic space group P1̄ (No. 2) with a = 11.0691(1) Å, b = 12.0451(1) Å, c = 12.9558(2) Å. α = 62.531(1)°, β = 69.544(1)°, γ = 76.181(1)°, V = 1429.71(3) Å 3 and Z = 1 {d calcd = 1.700 g/cm 3 ; μ a (Mo Kα) = 0.45 mm -1 }. A comparison of the X-ray crystal structure data from Co(F 28 TPP)·2tol and Co(F 28 TPP)·2THF indicates that the porphyrin core expands dramatically (0.08 Å) in the six-coordinate complex. Optical and 19 F NMR spectroscopic studies of Co(F 28 TPP) in the presence of added ligand demonstrate that spin-state modulation of the six-coordinate Co(II) center is facile. Partial population of the 4 E g state is accessed upon coordination of the cobalt center with THF σ-donor ligands, while six-coordinate complexes with 1-methylimidazole result in complete conversion to the high spin state, as evinced by 280 ppm downfield chemical shifts for the β-fluorine resonances in the 19 F NMR spectrum. Co(F 28 TPP) is the first example of a porphyrin which supports a high-spin cobalt ion.

AB - The syntheses and characterization of [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphinato]cobalt, Co(F 8 TPP), and [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl) porphinato]cobalt, Co(F 28 TPP), are reported. Co(F 28 TPP)·2tol (tol = toluene) crystallizes in the monoclinic space group C2/c-C h (No. 15) with a = 22.1616(5) Å, b = 12.0274(3) Å, c = 19.9159(2) Å, β = 110.645(1)°, V = 4967.6(2) Å 3 , and Z = 4 {d calcd = 1.818 g/cm 3 ; μ a (Mo Kα) = 0.50 mm -1 }, and Co(F 28 TPP)·2THF crystallizes in the triclinic space group P1̄ (No. 2) with a = 11.0691(1) Å, b = 12.0451(1) Å, c = 12.9558(2) Å. α = 62.531(1)°, β = 69.544(1)°, γ = 76.181(1)°, V = 1429.71(3) Å 3 and Z = 1 {d calcd = 1.700 g/cm 3 ; μ a (Mo Kα) = 0.45 mm -1 }. A comparison of the X-ray crystal structure data from Co(F 28 TPP)·2tol and Co(F 28 TPP)·2THF indicates that the porphyrin core expands dramatically (0.08 Å) in the six-coordinate complex. Optical and 19 F NMR spectroscopic studies of Co(F 28 TPP) in the presence of added ligand demonstrate that spin-state modulation of the six-coordinate Co(II) center is facile. Partial population of the 4 E g state is accessed upon coordination of the cobalt center with THF σ-donor ligands, while six-coordinate complexes with 1-methylimidazole result in complete conversion to the high spin state, as evinced by 280 ppm downfield chemical shifts for the β-fluorine resonances in the 19 F NMR spectrum. Co(F 28 TPP) is the first example of a porphyrin which supports a high-spin cobalt ion.

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