Solution-blended sulfonated polyphenylene and branched poly(arylene ether sulfone)

Synthesis, state of water, surface energy, proton transport, and fuel cell performance

Behrooz Motealleh, Fei Huang, Timothy D. Largier, Wayz Khan, Christopher J Cornelius

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A poly(arylene ether sulfone) (PAES) was synthesized with a sulfonated poly(phenyl sulfone) side-chain (sB) to create a branched sBPAES ionomer. This sBPAES ionomer was solution blended with sulfonated polyphenylene (sPP). The sulfonated side-chain dramatically improved miscibility between these distinctly different ionomers. This functional group facilitated their solution-casting into robust films that were flexible and tough. Ionomer film proton conductivity, water uptake, density, state-of-water, contact angle, surface energy, wide angle x-ray scattering, and hydrogen fuel-cell function were studied based upon blend concentration. Results showed that sPP blended with 5 wt% sBPAES had a relative free water content that increased by 97% as compared to unblended sPP. Ionomer blends containing 10 wt% sBPAES reduced the film's water uptake by 37.5% and only caused a 3.3% decrease in proton conductivity from 97.5 to 94.3 mS/cm. The relative free water concentration improved within the blend up to 10 wt% sBPAES. These improvements were attributed to changes in ion clustering noted using wide angle x-ray scattering. The film's apparent water contact angle revealed that introducing 10 wt % sBPAES into sPP lowered its surface energy from 27.2 mJ/m2 to 24.3 mJ/m2. This led to a higher membrane-electrode interfacial resistance for these ionomer-blended films. An optimal ionomer-blend containing 5 wt% sBPAES had a H2/O2 peak-power output of 630 mW/cm2 at 1490 mA/cm2, which was greater than its unmodified sPP version of 570 mW/cm2 and 1220 mA/cm2.

Original languageEnglish (US)
Pages (from-to)148-161
Number of pages14
JournalPolymer
Volume160
DOIs
StatePublished - Jan 3 2019

Fingerprint

Sulfones
Ionomers
Interfacial energy
Ether
Protons
Fuel cells
Ethers
Water
Proton conductivity
Contact angle
Scattering
X rays
Hydrogen fuels
polyphenylene sulfide
Water content
Functional groups
Casting
Solubility
Ions
Membranes

Keywords

  • Hydrogen fuel-cell
  • Ion transport and state-of-water
  • Ionomer blends

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Solution-blended sulfonated polyphenylene and branched poly(arylene ether sulfone) : Synthesis, state of water, surface energy, proton transport, and fuel cell performance. / Motealleh, Behrooz; Huang, Fei; Largier, Timothy D.; Khan, Wayz; Cornelius, Christopher J.

In: Polymer, Vol. 160, 03.01.2019, p. 148-161.

Research output: Contribution to journalArticle

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title = "Solution-blended sulfonated polyphenylene and branched poly(arylene ether sulfone): Synthesis, state of water, surface energy, proton transport, and fuel cell performance",
abstract = "A poly(arylene ether sulfone) (PAES) was synthesized with a sulfonated poly(phenyl sulfone) side-chain (sB) to create a branched sBPAES ionomer. This sBPAES ionomer was solution blended with sulfonated polyphenylene (sPP). The sulfonated side-chain dramatically improved miscibility between these distinctly different ionomers. This functional group facilitated their solution-casting into robust films that were flexible and tough. Ionomer film proton conductivity, water uptake, density, state-of-water, contact angle, surface energy, wide angle x-ray scattering, and hydrogen fuel-cell function were studied based upon blend concentration. Results showed that sPP blended with 5 wt{\%} sBPAES had a relative free water content that increased by 97{\%} as compared to unblended sPP. Ionomer blends containing 10 wt{\%} sBPAES reduced the film's water uptake by 37.5{\%} and only caused a 3.3{\%} decrease in proton conductivity from 97.5 to 94.3 mS/cm. The relative free water concentration improved within the blend up to 10 wt{\%} sBPAES. These improvements were attributed to changes in ion clustering noted using wide angle x-ray scattering. The film's apparent water contact angle revealed that introducing 10 wt {\%} sBPAES into sPP lowered its surface energy from 27.2 mJ/m2 to 24.3 mJ/m2. This led to a higher membrane-electrode interfacial resistance for these ionomer-blended films. An optimal ionomer-blend containing 5 wt{\%} sBPAES had a H2/O2 peak-power output of 630 mW/cm2 at 1490 mA/cm2, which was greater than its unmodified sPP version of 570 mW/cm2 and 1220 mA/cm2.",
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T2 - Synthesis, state of water, surface energy, proton transport, and fuel cell performance

AU - Motealleh, Behrooz

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AU - Largier, Timothy D.

AU - Khan, Wayz

AU - Cornelius, Christopher J

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N2 - A poly(arylene ether sulfone) (PAES) was synthesized with a sulfonated poly(phenyl sulfone) side-chain (sB) to create a branched sBPAES ionomer. This sBPAES ionomer was solution blended with sulfonated polyphenylene (sPP). The sulfonated side-chain dramatically improved miscibility between these distinctly different ionomers. This functional group facilitated their solution-casting into robust films that were flexible and tough. Ionomer film proton conductivity, water uptake, density, state-of-water, contact angle, surface energy, wide angle x-ray scattering, and hydrogen fuel-cell function were studied based upon blend concentration. Results showed that sPP blended with 5 wt% sBPAES had a relative free water content that increased by 97% as compared to unblended sPP. Ionomer blends containing 10 wt% sBPAES reduced the film's water uptake by 37.5% and only caused a 3.3% decrease in proton conductivity from 97.5 to 94.3 mS/cm. The relative free water concentration improved within the blend up to 10 wt% sBPAES. These improvements were attributed to changes in ion clustering noted using wide angle x-ray scattering. The film's apparent water contact angle revealed that introducing 10 wt % sBPAES into sPP lowered its surface energy from 27.2 mJ/m2 to 24.3 mJ/m2. This led to a higher membrane-electrode interfacial resistance for these ionomer-blended films. An optimal ionomer-blend containing 5 wt% sBPAES had a H2/O2 peak-power output of 630 mW/cm2 at 1490 mA/cm2, which was greater than its unmodified sPP version of 570 mW/cm2 and 1220 mA/cm2.

AB - A poly(arylene ether sulfone) (PAES) was synthesized with a sulfonated poly(phenyl sulfone) side-chain (sB) to create a branched sBPAES ionomer. This sBPAES ionomer was solution blended with sulfonated polyphenylene (sPP). The sulfonated side-chain dramatically improved miscibility between these distinctly different ionomers. This functional group facilitated their solution-casting into robust films that were flexible and tough. Ionomer film proton conductivity, water uptake, density, state-of-water, contact angle, surface energy, wide angle x-ray scattering, and hydrogen fuel-cell function were studied based upon blend concentration. Results showed that sPP blended with 5 wt% sBPAES had a relative free water content that increased by 97% as compared to unblended sPP. Ionomer blends containing 10 wt% sBPAES reduced the film's water uptake by 37.5% and only caused a 3.3% decrease in proton conductivity from 97.5 to 94.3 mS/cm. The relative free water concentration improved within the blend up to 10 wt% sBPAES. These improvements were attributed to changes in ion clustering noted using wide angle x-ray scattering. The film's apparent water contact angle revealed that introducing 10 wt % sBPAES into sPP lowered its surface energy from 27.2 mJ/m2 to 24.3 mJ/m2. This led to a higher membrane-electrode interfacial resistance for these ionomer-blended films. An optimal ionomer-blend containing 5 wt% sBPAES had a H2/O2 peak-power output of 630 mW/cm2 at 1490 mA/cm2, which was greater than its unmodified sPP version of 570 mW/cm2 and 1220 mA/cm2.

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