SnCl4-mediated reaction of ozonides with allyltrimethylsilane

Formation of 1,2-dioxolanes

Patrick H Dussault, Xuejun Liu

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

SnC14-mediated reaction of ozonides (1,2,4-trioxolanes) with allyltrimethylsilane furnishes trimethylsilylmethyl-1,2-dioxolanes via metalated carbonyl oxides. The carbonyl oxides can arise through initial ionization of either the ether or peroxide oxygens.

Original languageEnglish (US)
Pages (from-to)6553-6556
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number36
DOIs
StatePublished - Sep 3 1999

Fingerprint

Dioxolanes
Oxides
Peroxides
Ether
Ionization
Oxygen
stannic chloride
allyltrimethylsilane
1,2,4-trioxane

Keywords

  • Allylation
  • Dioxolanes
  • Ozonides
  • Peroxides

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

SnCl4-mediated reaction of ozonides with allyltrimethylsilane : Formation of 1,2-dioxolanes. / Dussault, Patrick H; Liu, Xuejun.

In: Tetrahedron Letters, Vol. 40, No. 36, 03.09.1999, p. 6553-6556.

Research output: Contribution to journalArticle

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