Singlet-triplet bistability in a 1,3-phenylene-based bis(aminoxyl) diradical

Andrzej Rajca, Kan Lu, Suchada Rajca, Charles R. Ross

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Rapid quenching of the title bis(aminoxyl) 1 in 2-methyltetrahydrofuran from ambient temperature to cryogenic temperatures (5 K or below) produces 1 in its singlet state, which slowly converts at low temperatures, with an S-shaped time-dependence, to the triplet ground state.

Original languageEnglish (US)
Pages (from-to)1249-1250
Number of pages2
JournalChemical Communications
Issue number13
DOIs
StatePublished - Jul 7 1999

Fingerprint

Rapid quenching
Cryogenics
Temperature
Ground state
2-methyltetrahydrofuran

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Singlet-triplet bistability in a 1,3-phenylene-based bis(aminoxyl) diradical. / Rajca, Andrzej; Lu, Kan; Rajca, Suchada; Ross, Charles R.

In: Chemical Communications, No. 13, 07.07.1999, p. 1249-1250.

Research output: Contribution to journalArticle

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