Singlet-triplet bistability in a 1,3-phenylene-based bis(aminoxyl) diradical

Andrzej Rajca, Kan Lu, Suchada Rajca, Charles R. Ross

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

Rapid quenching of the title bis(aminoxyl) 1 in 2-methyltetrahydrofuran from ambient temperature to cryogenic temperatures (5 K or below) produces 1 in its singlet state, which slowly converts at low temperatures, with an S-shaped time-dependence, to the triplet ground state.

Original languageEnglish (US)
Pages (from-to)1249-1250
Number of pages2
JournalChemical Communications
Issue number13
DOIs
StatePublished - Jul 7 1999

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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