Serial ligand catalysis: A highly selective allylic C-H oxidation

Mark S. Chen, Narayanasamy Prabagaran, Nathan A. Labenz, M. Christina White

Research output: Contribution to journalArticle

302 Citations (Scopus)

Abstract

We are reporting a mild, chemo-, and highly regioselective Pd(II)-catalyzed allylic oxidation of α-olefins to furnish branched allylic esters that proceeds via a novel serial ligand catalysis mechanism in which two different ligands (i.e., vinyl sulfoxide 2 and BQ) interact sequentially with the metal to promote distinct steps of the catalytic cycle (i.e., C-H cleavage and π-allyl functionalization, respectively).

Original languageEnglish (US)
Pages (from-to)6970-6971
Number of pages2
JournalJournal of the American Chemical Society
Volume127
Issue number19
DOIs
StatePublished - May 18 2005

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sulfoxide
Catalysis
Ligands
Oxidation
Alkenes
Olefins
Esters
Metals

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Serial ligand catalysis : A highly selective allylic C-H oxidation. / Chen, Mark S.; Prabagaran, Narayanasamy; Labenz, Nathan A.; White, M. Christina.

In: Journal of the American Chemical Society, Vol. 127, No. 19, 18.05.2005, p. 6970-6971.

Research output: Contribution to journalArticle

Chen, Mark S. ; Prabagaran, Narayanasamy ; Labenz, Nathan A. ; White, M. Christina. / Serial ligand catalysis : A highly selective allylic C-H oxidation. In: Journal of the American Chemical Society. 2005 ; Vol. 127, No. 19. pp. 6970-6971.
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