Sensitization of near-infrared-emitting lanthanide cations in solution by tropolonate ligands

Jian Zhang, Paul D. Badger, Steven J. Geib, Stéphane Petoud

Research output: Contribution to journalArticle

195 Citations (Scopus)

Abstract

(Graph Presented) One ligand, five NIR-emitting complexes: Tropolonate (trp) ligands sensitize the near-infrared emission of several lanthanide (LnIII) ions upon formation of [Ln-(trp)4]- complexes (Ln = Nd, Ho, Er, Tm, and Yb; see emission spectra). The solid-state structures and solution-state photophysical properties of the [Ln(trp) 4]- complexes have been characterized.

Original languageEnglish (US)
Pages (from-to)2508-2512
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number17
DOIs
StatePublished - Apr 22 2005

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Lanthanoid Series Elements
Rare earth elements
Cations
Positive ions
Ligands
Infrared radiation
Ions

Keywords

  • Lanthanides
  • Luminescence
  • Near-infrared emitters
  • O ligands
  • Sensitizers

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Sensitization of near-infrared-emitting lanthanide cations in solution by tropolonate ligands. / Zhang, Jian; Badger, Paul D.; Geib, Steven J.; Petoud, Stéphane.

In: Angewandte Chemie - International Edition, Vol. 44, No. 17, 22.04.2005, p. 2508-2512.

Research output: Contribution to journalArticle

Zhang, Jian ; Badger, Paul D. ; Geib, Steven J. ; Petoud, Stéphane. / Sensitization of near-infrared-emitting lanthanide cations in solution by tropolonate ligands. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 17. pp. 2508-2512.
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