Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

Kostiantyn O. Marichev, James M Takacs

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

Original languageEnglish (US)
Pages (from-to)2205-2210
Number of pages6
JournalACS Catalysis
Volume6
Issue number4
DOIs
StatePublished - Apr 1 2016

Fingerprint

Amination
Diamines
Ruthenium
Cyclization
Hydrogen
Alcohols

Keywords

  • aminations
  • borrowing hydrogen
  • heterocycle synthesis
  • hydrogen autotransfer
  • ruthenium(II) complex

ASJC Scopus subject areas

  • Catalysis

Cite this

Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology. / Marichev, Kostiantyn O.; Takacs, James M.

In: ACS Catalysis, Vol. 6, No. 4, 01.04.2016, p. 2205-2210.

Research output: Contribution to journalArticle

@article{588d62f81b0f4a9aaefe78242517387b,
title = "Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology",
abstract = "A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.",
keywords = "aminations, borrowing hydrogen, heterocycle synthesis, hydrogen autotransfer, ruthenium(II) complex",
author = "Marichev, {Kostiantyn O.} and Takacs, {James M}",
year = "2016",
month = "4",
day = "1",
doi = "10.1021/acscatal.6b00175",
language = "English (US)",
volume = "6",
pages = "2205--2210",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "4",

}

TY - JOUR

T1 - Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

AU - Marichev, Kostiantyn O.

AU - Takacs, James M

PY - 2016/4/1

Y1 - 2016/4/1

N2 - A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

AB - A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

KW - aminations

KW - borrowing hydrogen

KW - heterocycle synthesis

KW - hydrogen autotransfer

KW - ruthenium(II) complex

UR - http://www.scopus.com/inward/record.url?scp=84963548513&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84963548513&partnerID=8YFLogxK

U2 - 10.1021/acscatal.6b00175

DO - 10.1021/acscatal.6b00175

M3 - Article

VL - 6

SP - 2205

EP - 2210

JO - ACS Catalysis

JF - ACS Catalysis

SN - 2155-5435

IS - 4

ER -