Recyclable Magnetite Nanoparticle Catalyst for One-Pot Conversion of Cellobiose to 5-Hydroxymethylfurfural in Water

Anuja Bhalkikar, Zane C. Gernhart, Chin Li Cheung

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Abstract

Environmentally benign and easily recoverable magnetite nanoparticles (Fe3O4 NPs) were demonstrated to catalyze the one-pot conversion of cellobiose, a glucose disaccharide, to 5-hydroxymethylfurfural (5-HMF). The conversion was achieved in water under hydrothermal conditions. The catalytic activity of Fe3O4 NPs surpassed those of iron (II) and iron (III) chlorides in this reaction. Optimized cellobiose conversion reactions catalyzed with Fe3O4 NPs gave the highest 5-HMF yields of 23.4 ± 0.6% at 160°C for 24 hours. After three reuses, the Fe3O4 NP catalyst retained its catalytic activity with similar 5-HMF yields, demonstrating the recyclability of this eco-friendly catalyst in water.

Original languageEnglish (US)
Article number264037
JournalJournal of Nanomaterials
Volume2015
DOIs
Publication statusPublished - Jan 1 2015

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ASJC Scopus subject areas

  • Materials Science(all)

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