Protonation Nitrogen Shielding and NOE in Aqueous Nitrite and Solid-State 15N NMR of NOBF4 and NO2BF4

Younghee Ko, Francis T. Bonner, George B. Crull, Gerard S. Harbison

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Nitrogen-15 chemical shift measurements carried out under NO at 1 atm and pH ≥ 2.2 yield the value Δ(δ15N) = −30.4 ppm for the total protonation shielding of NO2(aq). Measurements at higher acidity levels reflect the increasing significance of NO+ and confirm the presence of two 15N resonances, one sharp and one broadened, in the region around 45% D2SO4. Assignment of the sharp peak to NO+ is confirmed by solid-state NMR of NOBF4. Broadening in the other suggests that exchange between HNO2 and some form of acidium ion (e.g. H2NO2+) precedes NO+ release, but no NOE is detected in 42.4% D2SO4 and it is inferred that no proton-to-nitrogen connnectivity occurs in this species. Nitrogen-15 chemical shifts and chemical shift anisotropics have been obtained in the solid state at natural isotopic abundance for the nitrosonium and nitronium ions in their respective tetrafluoroboride salts.

Original languageEnglish (US)
Pages (from-to)3316-3319
Number of pages4
JournalInorganic Chemistry
Volume32
Issue number15
DOIs
StatePublished - Jan 1 1993

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nitrites
Protonation
Chemical shift
Nitrites
nitrogen 15
Shielding
shielding
chemical equilibrium
Nitrogen
Nuclear magnetic resonance
solid state
nitrogen
nuclear magnetic resonance
Acidity
acidity
Protons
ions
Salts
Ions
salts

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Protonation Nitrogen Shielding and NOE in Aqueous Nitrite and Solid-State 15N NMR of NOBF4 and NO2BF4. / Ko, Younghee; Bonner, Francis T.; Crull, George B.; Harbison, Gerard S.

In: Inorganic Chemistry, Vol. 32, No. 15, 01.01.1993, p. 3316-3319.

Research output: Contribution to journalArticle

Ko, Younghee ; Bonner, Francis T. ; Crull, George B. ; Harbison, Gerard S. / Protonation Nitrogen Shielding and NOE in Aqueous Nitrite and Solid-State 15N NMR of NOBF4 and NO2BF4. In: Inorganic Chemistry. 1993 ; Vol. 32, No. 15. pp. 3316-3319.
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N2 - Nitrogen-15 chemical shift measurements carried out under NO at 1 atm and pH ≥ 2.2 yield the value Δ(δ15N) = −30.4 ppm for the total protonation shielding of NO2−(aq). Measurements at higher acidity levels reflect the increasing significance of NO+ and confirm the presence of two 15N resonances, one sharp and one broadened, in the region around 45% D2SO4. Assignment of the sharp peak to NO+ is confirmed by solid-state NMR of NOBF4. Broadening in the other suggests that exchange between HNO2 and some form of acidium ion (e.g. H2NO2+) precedes NO+ release, but no NOE is detected in 42.4% D2SO4 and it is inferred that no proton-to-nitrogen connnectivity occurs in this species. Nitrogen-15 chemical shifts and chemical shift anisotropics have been obtained in the solid state at natural isotopic abundance for the nitrosonium and nitronium ions in their respective tetrafluoroboride salts.

AB - Nitrogen-15 chemical shift measurements carried out under NO at 1 atm and pH ≥ 2.2 yield the value Δ(δ15N) = −30.4 ppm for the total protonation shielding of NO2−(aq). Measurements at higher acidity levels reflect the increasing significance of NO+ and confirm the presence of two 15N resonances, one sharp and one broadened, in the region around 45% D2SO4. Assignment of the sharp peak to NO+ is confirmed by solid-state NMR of NOBF4. Broadening in the other suggests that exchange between HNO2 and some form of acidium ion (e.g. H2NO2+) precedes NO+ release, but no NOE is detected in 42.4% D2SO4 and it is inferred that no proton-to-nitrogen connnectivity occurs in this species. Nitrogen-15 chemical shifts and chemical shift anisotropics have been obtained in the solid state at natural isotopic abundance for the nitrosonium and nitronium ions in their respective tetrafluoroboride salts.

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