One-pot formation of large macrocycles with modifiable peripheries and internal cavities

Joseph S. Ferguson, Kazuhiro Yamato, Rui Liu, Lan He, Xiao Cheng Zeng, Bing Gong

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

The shape of things to come: Aromatic oligohydrazide macrocycles with planar backbones enforced by three-center hydrogen bonds are formed in high yield from monomeric diacid chlorides and dihydrazides. Macrocycles consisting of six meta-linked pyridine and benzene residues have an internal cavity of about 10 Å diameter, while those with alternating meta- and para-linked benzene residues are larger and contain multiple convergent sites (see picture).

Original languageEnglish (US)
Pages (from-to)3150-3154
Number of pages5
JournalAngewandte Chemie - International Edition
Volume48
Issue number17
DOIs
StatePublished - Apr 14 2009

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Benzene
Pyridine
Chlorides
Hydrogen bonds
pyridine

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

One-pot formation of large macrocycles with modifiable peripheries and internal cavities. / Ferguson, Joseph S.; Yamato, Kazuhiro; Liu, Rui; He, Lan; Zeng, Xiao Cheng; Gong, Bing.

In: Angewandte Chemie - International Edition, Vol. 48, No. 17, 14.04.2009, p. 3150-3154.

Research output: Contribution to journalArticle

Ferguson, Joseph S. ; Yamato, Kazuhiro ; Liu, Rui ; He, Lan ; Zeng, Xiao Cheng ; Gong, Bing. / One-pot formation of large macrocycles with modifiable peripheries and internal cavities. In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 17. pp. 3150-3154.
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