Natural-Abundance Oxygen-17 NMR Spectra of Ozonides

F. Hock, V. Ball, Y. Dong, S. H. Gutsche, M. Hilss, K. Schlindwein, K. Griesbaum

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The natural-abundance 17O NMR spectra of 35 ozonides have been examined with the following results: Symmetrically tetrasubstituted ozonides and symmetrically disubstituted ozonides give only one signal each for the ether and the peroxide O atoms. Unsymmetrically tetrasubstituted ozonides bearing the electron-withdrawing groups CI, CN, or CF3, and also some unsymmetrically disubstituted ozonides, give two signals for the per oxide O atoms. Electron-withdrawing groups and ring stress in bicyclic ozonides cause downfield shifts in the -O-O- signals and even larger ones in the -O- signals. The range in which the signals appeared was 87-172 ppm for the ether O atoms and 263-336 ppm for the peroxide O atoms.

Original languageEnglish (US)
Pages (from-to)150-154
Number of pages5
JournalJournal of Magnetic Resonance, Series A
Volume111
Issue number2
DOIs
StatePublished - Jan 1 1994

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oxygen 17
ozonides
Nuclear magnetic resonance
Oxygen
Atoms
nuclear magnetic resonance
Peroxides
Ethers
Bearings (structural)
peroxides
Ether
atoms
Electrons
ethers
Oxides
1,2,4-trioxane
electrons
oxides
causes
rings

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Hock, F., Ball, V., Dong, Y., Gutsche, S. H., Hilss, M., Schlindwein, K., & Griesbaum, K. (1994). Natural-Abundance Oxygen-17 NMR Spectra of Ozonides. Journal of Magnetic Resonance, Series A, 111(2), 150-154. https://doi.org/10.1006/jmra.1994.1240

Natural-Abundance Oxygen-17 NMR Spectra of Ozonides. / Hock, F.; Ball, V.; Dong, Y.; Gutsche, S. H.; Hilss, M.; Schlindwein, K.; Griesbaum, K.

In: Journal of Magnetic Resonance, Series A, Vol. 111, No. 2, 01.01.1994, p. 150-154.

Research output: Contribution to journalArticle

Hock, F, Ball, V, Dong, Y, Gutsche, SH, Hilss, M, Schlindwein, K & Griesbaum, K 1994, 'Natural-Abundance Oxygen-17 NMR Spectra of Ozonides', Journal of Magnetic Resonance, Series A, vol. 111, no. 2, pp. 150-154. https://doi.org/10.1006/jmra.1994.1240
Hock, F. ; Ball, V. ; Dong, Y. ; Gutsche, S. H. ; Hilss, M. ; Schlindwein, K. ; Griesbaum, K. / Natural-Abundance Oxygen-17 NMR Spectra of Ozonides. In: Journal of Magnetic Resonance, Series A. 1994 ; Vol. 111, No. 2. pp. 150-154.
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