Nanostructure of a high-permeability, hydrogen-selective inorganic membrane

S. T. Oyama, D. Lee, P. Hacarlioglu, Y. Gu, Ravi F Saraf

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This paper describes the preparation and properties of an inorganic membrane with permeability for H2 comparable to palladium and with over 99.9% selectivity over larger species like CO, CO2 and CH 4. The membrane is a composite formed by the deposition of a thin, 20 nm SiO2 layer on an alumina support. The alumina support is obtained by the deposition of a boehmite sol on top of a porous substrate, so as to create a uniform structure with small pore sizes. The permeation of the small gas species, H2, He, and Ne through the silica layer is analyzed in detail in order to obtain insight about the transport mechanism and the structure of the silica. The order of permeance through the silica layer is highly unusual, He > H2 > Ne, following neither molecular weight nor size. The order of permeation is quantitatively explained using a statistical mechanics approach, which takes into consideration the density of solubility sites for the various species and the vibrational frequency of the species within the sites. An extension of the Masaryk-Fulrath treatment for glasses combined with the Percus-Yevick model is used to estimate the vibrational frequency (7.0×1012 s-1), solubility site density (3.0×1026 m-3 for H2) and the average distance between sites (0.84 nm). This is the first time an inorganic membrane has been described in detail at the nanometer level.

Original languageEnglish (US)
Title of host publication2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004
EditorsM. Laudon, B. Romanowicz
Pages272-275
Number of pages4
StatePublished - Nov 2 2004
Externally publishedYes
Event2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004 - Boston, MA, United States
Duration: Mar 7 2004Mar 11 2004

Publication series

Name2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004
Volume3

Conference

Conference2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004
CountryUnited States
CityBoston, MA
Period3/7/043/11/04

Fingerprint

Nanostructures
Silica
Vibrational spectra
Membranes
Permeation
Hydrogen
Alumina
Solubility
Statistical mechanics
Sols
Palladium
Pore size
Molecular weight
Glass
Composite materials
Substrates
Gases

Keywords

  • Hydrogen permeation
  • Silica/alumina membrane
  • Solubility sites
  • Statistical mechanics theory

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Oyama, S. T., Lee, D., Hacarlioglu, P., Gu, Y., & Saraf, R. F. (2004). Nanostructure of a high-permeability, hydrogen-selective inorganic membrane. In M. Laudon, & B. Romanowicz (Eds.), 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004 (pp. 272-275). (2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004; Vol. 3).

Nanostructure of a high-permeability, hydrogen-selective inorganic membrane. / Oyama, S. T.; Lee, D.; Hacarlioglu, P.; Gu, Y.; Saraf, Ravi F.

2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004. ed. / M. Laudon; B. Romanowicz. 2004. p. 272-275 (2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004; Vol. 3).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Oyama, ST, Lee, D, Hacarlioglu, P, Gu, Y & Saraf, RF 2004, Nanostructure of a high-permeability, hydrogen-selective inorganic membrane. in M Laudon & B Romanowicz (eds), 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004. 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004, vol. 3, pp. 272-275, 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004, Boston, MA, United States, 3/7/04.
Oyama ST, Lee D, Hacarlioglu P, Gu Y, Saraf RF. Nanostructure of a high-permeability, hydrogen-selective inorganic membrane. In Laudon M, Romanowicz B, editors, 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004. 2004. p. 272-275. (2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004).
Oyama, S. T. ; Lee, D. ; Hacarlioglu, P. ; Gu, Y. ; Saraf, Ravi F. / Nanostructure of a high-permeability, hydrogen-selective inorganic membrane. 2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004. editor / M. Laudon ; B. Romanowicz. 2004. pp. 272-275 (2004 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2004).
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