Nanopod formation through gold nanoparticle templated and catalyzed cross-linking of polymers bearing pendant propargyl ethers

Ke Zhang, Joshua I. Cutler, Jian Zhang, Dan Zheng, Evelyn Auyeung, Chad A. Mirkin

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A novel method for synthesizing polymer nanopods from a linear polymer bearing pendant propargyl ether groups, using gold nanoparticles as both the template and the catalyst for the cross-linking reaction, is reported. The transformations involved in the cross-linking process are unprecedented on the surface of a gold particle. A tentative cross-linking mechanism is proposed.

Original languageEnglish (US)
Pages (from-to)15151-15153
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number43
DOIs
StatePublished - Nov 3 2010

Fingerprint

Bearings (structural)
Gold
Nanoparticles
Ethers
Polymers
Cross Reactions
Catalysts
propargyl ether

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Nanopod formation through gold nanoparticle templated and catalyzed cross-linking of polymers bearing pendant propargyl ethers. / Zhang, Ke; Cutler, Joshua I.; Zhang, Jian; Zheng, Dan; Auyeung, Evelyn; Mirkin, Chad A.

In: Journal of the American Chemical Society, Vol. 132, No. 43, 03.11.2010, p. 15151-15153.

Research output: Contribution to journalArticle

Zhang, Ke ; Cutler, Joshua I. ; Zhang, Jian ; Zheng, Dan ; Auyeung, Evelyn ; Mirkin, Chad A. / Nanopod formation through gold nanoparticle templated and catalyzed cross-linking of polymers bearing pendant propargyl ethers. In: Journal of the American Chemical Society. 2010 ; Vol. 132, No. 43. pp. 15151-15153.
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