Magnetic nanostructuring and overcoming Brown's paradox to realize extraordinary high-temperature energy products

Balamurugan Balasubramanian, Pinaki Mukherjee, Ralph Skomski, Priyanka Manchanda, Bhaskar Das, David J Sellmyer

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Nanoscience has been one of the outstanding driving forces in technology recently, arguably more so in magnetism than in any other branch of science and technology. Due to nanoscale bit size, a single computer hard disk is now able to store the text of 3,000,000 average-size books, and today's high-performance permanent magnets-found in hybrid cars, wind turbines, and disk drives-are nanostructured to a large degree. The nanostructures ideally are designed from Co- and Fe-rich building blocks without critical rare-earth elements, and often are required to exhibit high coercivity and magnetization at elevated temperatures of typically up to 180°C for many important permanent-magnet applications. Here we achieve this goal in exchange-coupled hard-soft composite films by effective nanostructuring of high-anisotropy HfCo7 nanoparticles with a high-magnetization Fe65Co35 phase. An analysis based on a model structure shows that the soft-phase addition improves the performance of the hard-magnetic material by mitigating Brown's paradox in magnetism, a substantial reduction of coercivity from the anisotropy field. The nanostructures exhibit a high room-temperature energy product of about 20.3 MGOe (161.5 kJ/m3), which is a record for a rare earth- or Pt-free magnetic material and retain values as high as 17.1 MGOe (136.1 kJ/m 3) at 180°C.

Original languageEnglish (US)
Article number6265
JournalScientific reports
Volume4
DOIs
StatePublished - Sep 2 2014

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paradoxes
magnetic materials
permanent magnets
coercivity
rare earth elements
magnetization
anisotropy
wind turbines
products
nanoparticles
composite materials
energy
room temperature
temperature

ASJC Scopus subject areas

  • General

Cite this

Magnetic nanostructuring and overcoming Brown's paradox to realize extraordinary high-temperature energy products. / Balasubramanian, Balamurugan; Mukherjee, Pinaki; Skomski, Ralph; Manchanda, Priyanka; Das, Bhaskar; Sellmyer, David J.

In: Scientific reports, Vol. 4, 6265, 02.09.2014.

Research output: Contribution to journalArticle

Balasubramanian, Balamurugan ; Mukherjee, Pinaki ; Skomski, Ralph ; Manchanda, Priyanka ; Das, Bhaskar ; Sellmyer, David J. / Magnetic nanostructuring and overcoming Brown's paradox to realize extraordinary high-temperature energy products. In: Scientific reports. 2014 ; Vol. 4.
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