Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons

Dmitry V. Kosynkin, Amanda L. Higginbotham, Alexander Sinitskii, Jay R. Lomeda, Ayrat Dimiev, B. Katherine Price, James M. Tour

Research output: Contribution to journalArticle

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Abstract

Graphene, or single-layered graphite, with its high crystallinity and interesting semimetal electronic properties, has emerged as an exciting two-dimensional material showing great promise for the fabrication of nanoscale devices. Thin, elongated strips of graphene that possess straight edges, termed graphene ribbons, gradually transform from semiconductors to semimetals as their width increases, and represent a particularly versatile variety of graphene. Several lithographic, chemical and synthetic procedures are known to produce microscopic samples of graphene nanoribbons, and one chemical vapour deposition process has successfully produced macroscopic quantities of nanoribbons at 950°C. Here we describe a simple solution-based oxidative process for producing a nearly 100% yield of nanoribbon structures by lengthwise cutting and unravelling of multiwalled carbon nanotube (MWCNT) side walls. Although oxidative shortening of MWCNTs has previously been achieved, lengthwise cutting is hitherto unreported. Ribbon structures with high water solubility are obtained. Subsequent chemical reduction of the nanoribbons from MWCNTs results in restoration of electrical conductivity. These early results affording nanoribbons could eventually lead to applications in fields of electronics and composite materials where bulk quantities of nanoribbons are required.

Original languageEnglish (US)
Pages (from-to)872-876
Number of pages5
JournalNature
Volume458
Issue number7240
DOIs
StatePublished - Apr 16 2009

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Carbon Nanotubes
Graphite
Electric Conductivity
Semiconductors
Solubility
Equipment and Supplies
Water

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Cite this

Kosynkin, D. V., Higginbotham, A. L., Sinitskii, A., Lomeda, J. R., Dimiev, A., Price, B. K., & Tour, J. M. (2009). Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature, 458(7240), 872-876. https://doi.org/10.1038/nature07872

Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. / Kosynkin, Dmitry V.; Higginbotham, Amanda L.; Sinitskii, Alexander; Lomeda, Jay R.; Dimiev, Ayrat; Price, B. Katherine; Tour, James M.

In: Nature, Vol. 458, No. 7240, 16.04.2009, p. 872-876.

Research output: Contribution to journalArticle

Kosynkin, DV, Higginbotham, AL, Sinitskii, A, Lomeda, JR, Dimiev, A, Price, BK & Tour, JM 2009, 'Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons', Nature, vol. 458, no. 7240, pp. 872-876. https://doi.org/10.1038/nature07872
Kosynkin DV, Higginbotham AL, Sinitskii A, Lomeda JR, Dimiev A, Price BK et al. Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature. 2009 Apr 16;458(7240):872-876. https://doi.org/10.1038/nature07872
Kosynkin, Dmitry V. ; Higginbotham, Amanda L. ; Sinitskii, Alexander ; Lomeda, Jay R. ; Dimiev, Ayrat ; Price, B. Katherine ; Tour, James M. / Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. In: Nature. 2009 ; Vol. 458, No. 7240. pp. 872-876.
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