Lewis acid-mediated displacements of alkoxydioxolanes

Synthesis of a 1,2-dioxolane natural product

Patrick H Dussault, Xuejun Liu

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

(formula presented) Addition of electron-rich alkenes to the peroxycarbenium ions derived from Lewis acid-mediated ionization of 3-alkoxy-1,2-dioxolanes provides natural product related to the plakinic acids.

Original languageEnglish (US)
Pages (from-to)1391-1393
Number of pages3
JournalOrganic Letters
Volume1
Issue number9
DOIs
StatePublished - Nov 4 1999

Fingerprint

Dioxolanes
Lewis Acids
Alkenes
Biological Products
Ionization
Electrons
Ions
acids
Acids
synthesis
products
alkenes
ionization
ions
electrons
formal glycol
alkoxyl radical

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Lewis acid-mediated displacements of alkoxydioxolanes : Synthesis of a 1,2-dioxolane natural product. / Dussault, Patrick H; Liu, Xuejun.

In: Organic Letters, Vol. 1, No. 9, 04.11.1999, p. 1391-1393.

Research output: Contribution to journalArticle

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abstract = "(formula presented) Addition of electron-rich alkenes to the peroxycarbenium ions derived from Lewis acid-mediated ionization of 3-alkoxy-1,2-dioxolanes provides natural product related to the plakinic acids.",
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