Lead-Free Mixed Tin and Germanium Perovskites for Photovoltaic Application

Ming Gang Ju, Jun Dai, Liang Ma, Xiao Cheng Zeng

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

The power-conversion efficiency (PCE) of lead halide perovskite photovoltaics has reached 22.1% with significantly improved structural stability, thanks to a mixed cation and anion strategy. However, the mixing element strategy has not been widely seen in the design of lead-free perovskites for photovoltaic application. Herein, we report a comprehensive study of a series of lead-free and mixed tin and germanium halide perovskite materials. Most importantly, we predict that RbSn0.5Ge0.5I3 possesses not only a direct bandgap within the optimal range of 0.9-1.6 eV but also a desirable optical absorption spectrum that is comparable to those of the state-of-the-art methylammonium lead iodide perovskites, favorable effective masses for high carrier mobility, as well as a greater resistance to water penetration than the prototypical inorganic-organic lead-containing halide perovskite. If confirmed in the laboratory, this new lead-free inorganic perovskite may offer great promise as an alternative, highly efficient solar absorber material for photovoltaic application.

Original languageEnglish (US)
Pages (from-to)8038-8043
Number of pages6
JournalJournal of the American Chemical Society
Volume139
Issue number23
DOIs
StatePublished - Jun 14 2017

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Germanium
Tin
Lead
Perovskite
Solar absorbers
Carrier mobility
Iodides
Light absorption
Conversion efficiency
Anions
Cations
Absorption spectra
Energy gap
Negative ions
Positive ions
perovskite
Water

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Lead-Free Mixed Tin and Germanium Perovskites for Photovoltaic Application. / Ju, Ming Gang; Dai, Jun; Ma, Liang; Zeng, Xiao Cheng.

In: Journal of the American Chemical Society, Vol. 139, No. 23, 14.06.2017, p. 8038-8043.

Research output: Contribution to journalArticle

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