Isotope signature characterization of Pb and U in open air by laser-ablation mass spectrometry

Yun Shen Zhou, Yao Lu, Meng Meng Wang, Lei Liu, Xi Huang, Li Jia Jiang, Lan Jiang, Jean François Silvain, Yong Feng Lu

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1 Scopus citations

Abstract

Isotope signatures have attracted growing interest in recent years. In addition to the existing mass spectrometric (MS) techniques, demand for open-air and in situ analytical tools is increasing. Laser ablation is effective in atomizing and ionizing materials, and is frequently used in MS. However, light-isotope enrichment in laser-ablated plasma plumes has to be mitigated for accurate isotope analyses. In this letter, we reported an open-air laser-ablation mass spectrometric (OA-LAMS) technique to measure isotope signatures of Pb and U samples without sample pretreatments with improved accuracy in open air. The secondary cations, PbOH+ and UO2OH+, yielded more accurate isotope signatures regardless of environmental changes. This phenomenon was ascribed to different ionization schemes, in which the primary cations came from laser ionization of the samples and the secondary cations came from chemical ionization of the ablated neutral clusters. The results demonstrated the feasibility of the OA-LAMS method for characterizing isotope signatures.

Original languageEnglish (US)
Pages (from-to)1932-1937
Number of pages6
JournalJournal of Analytical Atomic Spectrometry
Volume32
Issue number10
DOIs
StatePublished - Oct 2017

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

Zhou, Y. S., Lu, Y., Wang, M. M., Liu, L., Huang, X., Jiang, L. J., Jiang, L., Silvain, J. F., & Lu, Y. F. (2017). Isotope signature characterization of Pb and U in open air by laser-ablation mass spectrometry. Journal of Analytical Atomic Spectrometry, 32(10), 1932-1937. https://doi.org/10.1039/c7ja00142h