(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

Tian Huey Lu, Tahir H. Tahirov, Yuh Liang Liu, Chung Sun Chung, Chiung Chia Huang, Yaw Shiun Hong

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.

Original languageEnglish (US)
Pages (from-to)1093-1095
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number5
DOIs
StatePublished - May 15 1996

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X-Ray Diffraction
Amines
Metals
Ions
Ligands
copper
Atoms
atoms
amines
Mirrors
Crystal structure
mirrors
X ray diffraction
ligands
crystal structure
Geometry
geometry
diffraction
metals
isothiocyanic acid

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN). / Lu, Tian Huey; Tahirov, Tahir H.; Liu, Yuh Liang; Chung, Chung Sun; Huang, Chiung Chia; Hong, Yaw Shiun.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 5, 15.05.1996, p. 1093-1095.

Research output: Contribution to journalArticle

Lu, Tian Huey ; Tahirov, Tahir H. ; Liu, Yuh Liang ; Chung, Chung Sun ; Huang, Chiung Chia ; Hong, Yaw Shiun. / (Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN). In: Acta Crystallographica Section C: Crystal Structure Communications. 1996 ; Vol. 52, No. 5. pp. 1093-1095.
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abstract = "The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.",
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T1 - (Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane] copper(II) thiocyanate, [Cu(NCS)(cyclam)](SCN)

AU - Lu, Tian Huey

AU - Tahirov, Tahir H.

AU - Liu, Yuh Liang

AU - Chung, Chung Sun

AU - Huang, Chiung Chia

AU - Hong, Yaw Shiun

PY - 1996/5/15

Y1 - 1996/5/15

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AB - The crystal structure of the title compound, [Cu(NCS)-(C10H24N4)](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The CuII ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position; its coordination geometry is normal, with the equatorial Cu - N distances shorter than the axial one. The unbound SCN- counterion is statistically disordered.

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