Isomer shift systematics of amorphous Fe-early transition metal and Fe-metalloid systems

C. L. Chien, Gang Xiao, S. H. Liou

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Isomer shift data in Fe-early transition metal and Fe-metalloid amorphous systems over wide composition range have been analyzed with the Miedema-van der Woude model of isomer shift in alloys. It is found that the model gives satisfactory description in some Fe-early transition metal systems, while in the others only the general trend is predicted. In the case of Fe-metalloid systems, a large deviation from the model is always observed at the Fe-poor side. This departure, which cannot be consistently accounted for by volume mismatch mechanism, is likely to be caused by hybridization effects.

Original languageEnglish (US)
Pages (from-to)373-376
Number of pages4
JournalHyperfine Interactions
Volume27
Issue number1-4
DOIs
StatePublished - Mar 1 1986

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Metalloids
metalloids
Isomers
Transition metals
isomers
transition metals
shift
deviation
trends
Chemical analysis

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Cite this

Isomer shift systematics of amorphous Fe-early transition metal and Fe-metalloid systems. / Chien, C. L.; Xiao, Gang; Liou, S. H.

In: Hyperfine Interactions, Vol. 27, No. 1-4, 01.03.1986, p. 373-376.

Research output: Contribution to journalArticle

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