Isolation of the triplet ground state aminyl diradical

Przemysław J. Boratyński, Maren Pink, Suchada Rajca, Andrzej Rajca

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Spin cycle: A high-spin nitrogen-centered (aminyl) diradical with a triplet (S = 1) ground state (see picture) has a large singlet-triplet energy gap (ΔEST) Effective shielding of the reactive aminyl radical centers provides stability at room temperature and maintains the planarity of the π system required for the triplet ground state and large ΔE ST value. The diradical assembles in solution to form a π-dimer-like structure with weak exchange coupling. (Figure Presented)

Original languageEnglish (US)
Pages (from-to)5459-5462
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number32
DOIs
StatePublished - Jul 26 2010

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Ground state
Exchange coupling
Dimers
Shielding
Energy gap
Nitrogen
Temperature

Keywords

  • Amines
  • Dimerization
  • Interactions
  • Radicals
  • Reactive intermediates
  • π

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Isolation of the triplet ground state aminyl diradical. / Boratyński, Przemysław J.; Pink, Maren; Rajca, Suchada; Rajca, Andrzej.

In: Angewandte Chemie - International Edition, Vol. 49, No. 32, 26.07.2010, p. 5459-5462.

Research output: Contribution to journalArticle

Boratyński, Przemysław J. ; Pink, Maren ; Rajca, Suchada ; Rajca, Andrzej. / Isolation of the triplet ground state aminyl diradical. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 32. pp. 5459-5462.
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