Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

James M Takacs, Suresh Vayalakkada, Steven J. Mehrman, Celia L. Kingsbury

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.

Original languageEnglish (US)
Pages (from-to)8417-8420
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number46
DOIs
StatePublished - Nov 11 2002

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Cyclopentanes
Iron

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside. / Takacs, James M; Vayalakkada, Suresh; Mehrman, Steven J.; Kingsbury, Celia L.

In: Tetrahedron Letters, Vol. 43, No. 46, 11.11.2002, p. 8417-8420.

Research output: Contribution to journalArticle

Takacs, James M ; Vayalakkada, Suresh ; Mehrman, Steven J. ; Kingsbury, Celia L. / Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside. In: Tetrahedron Letters. 2002 ; Vol. 43, No. 46. pp. 8417-8420.
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