Investigation of the interphase between recycled aggregates and cementitious binding materials using integrated microstructural-nanomechanical-chemical characterization

Mahdieh Khedmati, Yong Rak Kim, Joseph A. Turner

Research output: Contribution to journalArticle

Abstract

The mixtures including crushed recycled aggregates have multiple complex aggregate/paste interphase regions compared to conventional concrete mixtures, which brings significant technical challenges in understanding and characterization of their properties. To gain a better understanding of such complex material organization, this study adopted multiscale experimental methods by using nanoindentation test-analysis, laser scanning microscopy, and energy dispersive spectroscopy. The multiscale methods were applied to two different composites in which the same recycled aggregates were mixed with two different cementitious binders: a fly ash-based geopolymer and conventional Portland cement. The test-analysis results demonstrate that, in cement concrete mixtures with recycled aggregates (CCRA), the pre-existing incomplete interphase within the recycled aggregares was observed, although new paste was relatively well-bonded to the old recycled aggregate paste by having an approximately 20-μm thick interfacial transition zone. In geopolymer concrete mixtures with recycled aggregates (GCRA), both the old and new interphase appeared dense. More interestingly, the pre-existing incomplete interphase within the recycled aggregates was filled in the GCRA, which was not the case observed from the CCRA. Further analysis using energy dispersive spectroscopy suggests that geopolymeric materials can reach the pre-existing incomplete interphase and create hydration-geopolymerization products that combine calcium-silicate-hydrate (C-S-H) and sodium aluminosilicate hydrate (N-A-S-H) gel. The resulting cementitious composite is expected to show enhanced mechanical properties owing to a better interphase region.

LanguageEnglish (US)
Pages218-229
Number of pages12
JournalComposites Part B: Engineering
Volume158
DOIs
StatePublished - Feb 1 2019

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Concrete mixtures
Geopolymers
Ointments
Hydrates
Energy dispersive spectroscopy
Cements
Silicic Acid
Coal Ash
Calcium silicate
Aluminosilicates
Composite materials
Nanoindentation
Portland cement
Fly ash
Hydration
Binders
Microscopic examination
Gels
Sodium
Scanning

Keywords

  • Cementitious composites
  • Geopolymer
  • Interphase/interface
  • Recycled aggregate

ASJC Scopus subject areas

  • Ceramics and Composites
  • Mechanics of Materials
  • Mechanical Engineering
  • Industrial and Manufacturing Engineering

Cite this

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title = "Investigation of the interphase between recycled aggregates and cementitious binding materials using integrated microstructural-nanomechanical-chemical characterization",
abstract = "The mixtures including crushed recycled aggregates have multiple complex aggregate/paste interphase regions compared to conventional concrete mixtures, which brings significant technical challenges in understanding and characterization of their properties. To gain a better understanding of such complex material organization, this study adopted multiscale experimental methods by using nanoindentation test-analysis, laser scanning microscopy, and energy dispersive spectroscopy. The multiscale methods were applied to two different composites in which the same recycled aggregates were mixed with two different cementitious binders: a fly ash-based geopolymer and conventional Portland cement. The test-analysis results demonstrate that, in cement concrete mixtures with recycled aggregates (CCRA), the pre-existing incomplete interphase within the recycled aggregares was observed, although new paste was relatively well-bonded to the old recycled aggregate paste by having an approximately 20-μm thick interfacial transition zone. In geopolymer concrete mixtures with recycled aggregates (GCRA), both the old and new interphase appeared dense. More interestingly, the pre-existing incomplete interphase within the recycled aggregates was filled in the GCRA, which was not the case observed from the CCRA. Further analysis using energy dispersive spectroscopy suggests that geopolymeric materials can reach the pre-existing incomplete interphase and create hydration-geopolymerization products that combine calcium-silicate-hydrate (C-S-H) and sodium aluminosilicate hydrate (N-A-S-H) gel. The resulting cementitious composite is expected to show enhanced mechanical properties owing to a better interphase region.",
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AB - The mixtures including crushed recycled aggregates have multiple complex aggregate/paste interphase regions compared to conventional concrete mixtures, which brings significant technical challenges in understanding and characterization of their properties. To gain a better understanding of such complex material organization, this study adopted multiscale experimental methods by using nanoindentation test-analysis, laser scanning microscopy, and energy dispersive spectroscopy. The multiscale methods were applied to two different composites in which the same recycled aggregates were mixed with two different cementitious binders: a fly ash-based geopolymer and conventional Portland cement. The test-analysis results demonstrate that, in cement concrete mixtures with recycled aggregates (CCRA), the pre-existing incomplete interphase within the recycled aggregares was observed, although new paste was relatively well-bonded to the old recycled aggregate paste by having an approximately 20-μm thick interfacial transition zone. In geopolymer concrete mixtures with recycled aggregates (GCRA), both the old and new interphase appeared dense. More interestingly, the pre-existing incomplete interphase within the recycled aggregates was filled in the GCRA, which was not the case observed from the CCRA. Further analysis using energy dispersive spectroscopy suggests that geopolymeric materials can reach the pre-existing incomplete interphase and create hydration-geopolymerization products that combine calcium-silicate-hydrate (C-S-H) and sodium aluminosilicate hydrate (N-A-S-H) gel. The resulting cementitious composite is expected to show enhanced mechanical properties owing to a better interphase region.

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