Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers

Xin Zhang, Xu Zhang, Jacob A. Johnson, Yu Sheng Chen, Jian Zhang

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.

Original languageEnglish (US)
Pages (from-to)8380-8383
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number27
DOIs
StatePublished - Jul 13 2016

Fingerprint

Boron
Photooxidation
Zirconium
Metals
Chemical activation
Ligands
Topology
methylphenylsulfide
tris(2,2'-bipyridine)ruthenium II
bis(bipyridyl)ruthenium(II)

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers. / Zhang, Xin; Zhang, Xu; Johnson, Jacob A.; Chen, Yu Sheng; Zhang, Jian.

In: Journal of the American Chemical Society, Vol. 138, No. 27, 13.07.2016, p. 8380-8383.

Research output: Contribution to journalArticle

@article{d75e32c28c264f38bbd16f899ca1f131,
title = "Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers",
abstract = "Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6{\%}) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.",
author = "Xin Zhang and Xu Zhang and Johnson, {Jacob A.} and Chen, {Yu Sheng} and Jian Zhang",
year = "2016",
month = "7",
day = "13",
doi = "10.1021/jacs.6b04608",
language = "English (US)",
volume = "138",
pages = "8380--8383",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "27",

}

TY - JOUR

T1 - Highly Porous Zirconium Metal-Organic Frameworks with β-UH3-like Topology Based on Elongated Tetrahedral Linkers

AU - Zhang, Xin

AU - Zhang, Xu

AU - Johnson, Jacob A.

AU - Chen, Yu Sheng

AU - Zhang, Jian

PY - 2016/7/13

Y1 - 2016/7/13

N2 - Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.

AB - Two non-interpenetrated zirconium metal-organic frameworks (Zr-MOFs), NPF-200 and NPF-201, were synthesized via the assembly of elongated tetrahedral linkers with Zr6 and Zr8 clusters. They represent the first examples of MOFs to have the β-UH3-like, 4,12,12T1 topology. Upon activation, NPF-200 exhibits the largest BET surface area (5463 m2 g-1) and void volume (81.6%) among all MOFs formed from tetrahedral ligands. Composed of negative-charged boron-centered tetrahedral linkers, NPF-201 is an anionic Zr-MOF which selectively uptakes photoactive [Ru(bpy)3]2+ for heterogeneous photo-oxidation of thioanisole.

UR - http://www.scopus.com/inward/record.url?scp=84978864759&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84978864759&partnerID=8YFLogxK

U2 - 10.1021/jacs.6b04608

DO - 10.1021/jacs.6b04608

M3 - Article

C2 - 27341503

AN - SCOPUS:84978864759

VL - 138

SP - 8380

EP - 8383

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 27

ER -