High-Spin Organic Diradical with Robust Stability

Nolan M. Gallagher, Jackson J. Bauer, Maren Pink, Suchada Rajca, Andrzej Rajca

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

Triplet ground-state organic molecules are interesting with respect to several emerging technologies but typically exhibit limited stability. We report two organic diradicals, one of which possesses a triplet ground state (2J/kB = 234 ± 36 K) and robust stability at elevated temperatures. We are able to sublime this high-spin diradical under high vacuum at 140 °C with no significant decomposition.

Original languageEnglish (US)
Pages (from-to)9377-9380
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number30
DOIs
StatePublished - Aug 3 2016

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Vacuum
Ground state
Technology
Temperature
Decomposition
Molecules
Robust stability

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

High-Spin Organic Diradical with Robust Stability. / Gallagher, Nolan M.; Bauer, Jackson J.; Pink, Maren; Rajca, Suchada; Rajca, Andrzej.

In: Journal of the American Chemical Society, Vol. 138, No. 30, 03.08.2016, p. 9377-9380.

Research output: Contribution to journalArticle

Gallagher, Nolan M. ; Bauer, Jackson J. ; Pink, Maren ; Rajca, Suchada ; Rajca, Andrzej. / High-Spin Organic Diradical with Robust Stability. In: Journal of the American Chemical Society. 2016 ; Vol. 138, No. 30. pp. 9377-9380.
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