Fast atom bombardment mass spectrometry of related Cu(I) and Cu(II) chelates

Ronald Cerny, Maurice M. Bursey, Donald L. Jameson, Mitchell R. Malachowski, Thomas N. Sorrell

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reactions of a series of Cu(I) and Cu(II) complexes containing pyrazolyl or dimethylpyrazolyl residues in the ligands during the ionization process were studied by fast atom bombardment mass spectrometry. Complexes with a +1 charge produce intact cations. Those with a higher charge yield +1 cations by formal reduction or by clustering with anions, sometimes by several simultaneous processes. Neutral complexes are protonated to give +1 ions.

Original languageEnglish (US)
Pages (from-to)89-93
Number of pages5
JournalInorganica Chimica Acta
Volume89
Issue number2
DOIs
StatePublished - Oct 15 1984

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Fast Atom Bombardment Mass Spectrometry
chelates
Mass spectrometry
Cations
bombardment
mass spectroscopy
Positive ions
cations
Atoms
Ionization
Anions
Cluster Analysis
atoms
Negative ions
Ligands
Ions
anions
ionization
ligands
ions

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Fast atom bombardment mass spectrometry of related Cu(I) and Cu(II) chelates. / Cerny, Ronald; Bursey, Maurice M.; Jameson, Donald L.; Malachowski, Mitchell R.; Sorrell, Thomas N.

In: Inorganica Chimica Acta, Vol. 89, No. 2, 15.10.1984, p. 89-93.

Research output: Contribution to journalArticle

Cerny, Ronald ; Bursey, Maurice M. ; Jameson, Donald L. ; Malachowski, Mitchell R. ; Sorrell, Thomas N. / Fast atom bombardment mass spectrometry of related Cu(I) and Cu(II) chelates. In: Inorganica Chimica Acta. 1984 ; Vol. 89, No. 2. pp. 89-93.
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