Fast and eco-friendly fabrication of uniform Ag substrates for highly sensitive surface-enhanced Raman scattering

Yongda Xu, Xin Li, Lan Jiang, Ge Meng, Peng Ran, Yongfeng Lu

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

This study proposed a fast, simple, eco-friendly method for obtaining highly sensitive and uniform surface-enhanced Raman scattering (SERS) of silver (Ag) nanotextured substrates decorated with silver nanoparticles in open air. By splitting conventional femtosecond pulses (subpulse delay Δt = 0 ps) into pulse trains (subpulse delay Δt = 3 ps), the mean diameter of Ag nanoparticles was reduced by almost half and the amount of Ag nanoparticles with a diameter ranging from 20 to 60 nm was increased by more than 11 times. The substrate fabricated by femtosecond pulse trains has four main merits as follows: (1) High sensitivity: the maximum SERS enhancement factor is 1.26 × 109; (2) High efficiency: the fabrication rate can be up to 1600 μm2/s, which is 20–40 times faster than femtosecond photochemical reduction; (3) Good reproducibility: the relative standard deviation of the Raman signal intensity is 10.7%, which is one-third of that for conventional femtosecond laser; (4) Eco-friendly fabrication: neither chemical reagents nor vacuum conditions are needed during the fabrication process.

Original languageEnglish (US)
Article number322
JournalApplied Physics A: Materials Science and Processing
Volume123
Issue number5
DOIs
StatePublished - May 1 2017

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Ultrashort pulses
Raman scattering
Nanoparticles
Silver
Fabrication
Substrates
Vacuum
Air

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

Cite this

Fast and eco-friendly fabrication of uniform Ag substrates for highly sensitive surface-enhanced Raman scattering. / Xu, Yongda; Li, Xin; Jiang, Lan; Meng, Ge; Ran, Peng; Lu, Yongfeng.

In: Applied Physics A: Materials Science and Processing, Vol. 123, No. 5, 322, 01.05.2017.

Research output: Contribution to journalArticle

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abstract = "This study proposed a fast, simple, eco-friendly method for obtaining highly sensitive and uniform surface-enhanced Raman scattering (SERS) of silver (Ag) nanotextured substrates decorated with silver nanoparticles in open air. By splitting conventional femtosecond pulses (subpulse delay Δt = 0 ps) into pulse trains (subpulse delay Δt = 3 ps), the mean diameter of Ag nanoparticles was reduced by almost half and the amount of Ag nanoparticles with a diameter ranging from 20 to 60 nm was increased by more than 11 times. The substrate fabricated by femtosecond pulse trains has four main merits as follows: (1) High sensitivity: the maximum SERS enhancement factor is 1.26 × 109; (2) High efficiency: the fabrication rate can be up to 1600 μm2/s, which is 20–40 times faster than femtosecond photochemical reduction; (3) Good reproducibility: the relative standard deviation of the Raman signal intensity is 10.7{\%}, which is one-third of that for conventional femtosecond laser; (4) Eco-friendly fabrication: neither chemical reagents nor vacuum conditions are needed during the fabrication process.",
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