Fabrication and characterization of polyimide-zeolite L mixed matrix membranes for gas separations

Todd W. Pechar, Sangil Kim, Ben Vaughan, Eva Marand, Michael Tsapatsis, Hae Kwon Jeong, Christopher J Cornelius

Research output: Contribution to journalArticle

139 Citations (Scopus)

Abstract

Mixed matrix membranes composed of zeolite L dispersed in a 6FDA-6FpDA-DABA polyimide matrix were fabricated and characterized for gas separation performance. The interfacial contact between the two phases relied on introducing amine functional groups on the zeolite surface and covalently linking them with carboxylic acid groups present along the polyimide backbone. While certain gas permeabilities in the membranes increased with the addition of zeolite L, overall these mixed matrix membranes did not offer substantial selectivity improvements. Separate gravimetric sorption measurements indicated that the sorption capacity of zeolites modified with silane coupling agents is substantially lower than the gas sorption in unmodified zeolites.

Original languageEnglish (US)
Pages (from-to)195-202
Number of pages8
JournalJournal of Membrane Science
Volume277
Issue number1-2
DOIs
StatePublished - Jun 1 2006
Externally publishedYes

Fingerprint

Zeolites
polyimides
Polyimides
sorption
Sorption
Gases
membranes
Membranes
Fabrication
zeolites
fabrication
matrices
gases
Gas permeability
Coupling agents
Silanes
Carboxylic acids
carboxylic acids
silanes
Contacts (fluid mechanics)

Keywords

  • Gas separation
  • Mixed matrix membranes
  • Polymer membranes
  • Sorption
  • Zeolites

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

Cite this

Fabrication and characterization of polyimide-zeolite L mixed matrix membranes for gas separations. / Pechar, Todd W.; Kim, Sangil; Vaughan, Ben; Marand, Eva; Tsapatsis, Michael; Jeong, Hae Kwon; Cornelius, Christopher J.

In: Journal of Membrane Science, Vol. 277, No. 1-2, 01.06.2006, p. 195-202.

Research output: Contribution to journalArticle

Pechar, Todd W. ; Kim, Sangil ; Vaughan, Ben ; Marand, Eva ; Tsapatsis, Michael ; Jeong, Hae Kwon ; Cornelius, Christopher J. / Fabrication and characterization of polyimide-zeolite L mixed matrix membranes for gas separations. In: Journal of Membrane Science. 2006 ; Vol. 277, No. 1-2. pp. 195-202.
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