Enhanced electrocatalytic reduction of CO2/H2O to paraformaldehyde at Pt/metal oxide interfaces

Boxun Hu, Victor Stancovski, Martha Morton, Steven L. Suib

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A long-standing goal of chemistry is to synthesize organic compounds from CO2 and H2O to mimic natural photosynthetic processes. Achieving this goal requires catalysts and methods that activate CO2 and split water simultaneously. Here we report such catalysts and methods for the synthesis of paraformaldehyde from CO2 and H2O at atmospheric pressure. The activation was realized by polarizing metal/metal oxide interfaces with a DC voltage or current. The selectivity to paraformaldehyde was as high as 100% and CO2 conversion up to 8%. Both Pt/CSZ and Pt/MnO2 catalysts with ionic conductivity and mixed conductivity respectively produced paraformaldehyde. The former works at high temperatures of 600-900 °C; the latter works at low temperatures of 300-450 °C. This gas-phase electrocatalysis technique provides new insight into the utilization of CO2 as a carbon source in organic chemical syntheses and in the clean activation of CO2.

Original languageEnglish (US)
Pages (from-to)277-283
Number of pages7
JournalApplied Catalysis A: General
Volume382
Issue number2
DOIs
StatePublished - Jul 15 2010

Fingerprint

Oxides
Metals
Catalysts
Chemical activation
Organic Chemicals
Electrocatalysis
Organic chemicals
Ionic conductivity
Organic compounds
Atmospheric pressure
Carbon
Gases
Temperature
Water
Electric potential
paraform

Keywords

  • CO activation
  • Electrocatalysis
  • Formaldehyde
  • Platinum

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Enhanced electrocatalytic reduction of CO2/H2O to paraformaldehyde at Pt/metal oxide interfaces. / Hu, Boxun; Stancovski, Victor; Morton, Martha; Suib, Steven L.

In: Applied Catalysis A: General, Vol. 382, No. 2, 15.07.2010, p. 277-283.

Research output: Contribution to journalArticle

Hu, Boxun ; Stancovski, Victor ; Morton, Martha ; Suib, Steven L. / Enhanced electrocatalytic reduction of CO2/H2O to paraformaldehyde at Pt/metal oxide interfaces. In: Applied Catalysis A: General. 2010 ; Vol. 382, No. 2. pp. 277-283.
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