Energy gaps in "Metallic" single-walled carbon nanotubes

M. Ouyang, J. L. Huang, C. L. Cheung, C. M. Lieber

Research output: Contribution to journalArticle

562 Citations (Scopus)

Abstract

Metallic single-walled carbon nanotubes have been proposed to be good one-dimensional conductors. However, the finite curvature of the graphene sheet that forms the nanotubes and the broken symmetry due to the local environment may modify their electronic properties. We used low-temperature atomically resolved scanning tunneling microscopy to investigate zigzag and armchair nanotubes, both thought to be metallic. "Metallic" zigzag nanotubes were found to have energy gaps with magnitudes that depend inversely on the square of the tube radius, whereas isolated armchair tubes do not have energy gaps. Additionally, armchair nanotubes packed in bundles have pseudogaps, which exhibit an inverse dependence on tube radius. These observed energy gaps suggest that most "metallic" single-walled nanotubes are not true metals, and they have implications for our understanding of the electronic properties and potential applications of carbon nanotubes.

Original languageEnglish (US)
Pages (from-to)702-705
Number of pages4
JournalScience
Volume292
Issue number5517
DOIs
StatePublished - Apr 27 2001

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Nanotubes
Carbon Nanotubes
Scanning Tunnelling Microscopy
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Metals
Temperature

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Energy gaps in "Metallic" single-walled carbon nanotubes. / Ouyang, M.; Huang, J. L.; Cheung, C. L.; Lieber, C. M.

In: Science, Vol. 292, No. 5517, 27.04.2001, p. 702-705.

Research output: Contribution to journalArticle

Ouyang, M, Huang, JL, Cheung, CL & Lieber, CM 2001, 'Energy gaps in "Metallic" single-walled carbon nanotubes', Science, vol. 292, no. 5517, pp. 702-705. https://doi.org/10.1126/science.1058853
Ouyang, M. ; Huang, J. L. ; Cheung, C. L. ; Lieber, C. M. / Energy gaps in "Metallic" single-walled carbon nanotubes. In: Science. 2001 ; Vol. 292, No. 5517. pp. 702-705.
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