Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers

Alexey Lipatov, Haidong Lu, Mohamed Alhabeb, Babak Anasori, Alexei Gruverman, Yury Gogotsi, Alexander Sinitskii

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, are a large class of materials that are finding numerous applications ranging from energy storage and electromagnetic interference shielding to water purification and antibacterial coatings. Yet, despite the fact that more than 20 different MXenes have been synthesized, the mechanical properties of a MXene monolayer have not been experimentally studied. We measured the elastic properties of monolayers and bilayers of the most important MXene material to date, Ti3C2Tx (Tx stands for surface termination). We developed a method for preparing well-strained membranes of Ti3C2Tx monolayers and bilayers, and performed their nanoindentation with the tip of an atomic force microscope to record the force-displacement curves. The effective Young’s modulus of a single layer of Ti3C2Tx was found to be 0.33 ± 0.03 TPa, which is the highest among the mean values reported in nanoindentation experiments for other solution-processed 2D materials, including graphene oxide. This work opens a pathway for investigating the mechanical properties of monolayers and bilayers of other MXenes and extends the already broad range of MXenes’ applications to structural composites, protective coatings, nanoresonators, and membranes that require materials with exceptional mechanical properties.

Original languageEnglish (US)
Article numbereaat0491
JournalScience Advances
Volume4
Issue number6
DOIs
StatePublished - Jun 15 2018

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Monolayers
Nanoindentation
Mechanical properties
Membranes
Graphite
Protective coatings
Signal interference
Nitrides
Shielding
Energy storage
Oxides
Transition metals
Purification
Carbides
Microscopes
Elastic moduli
Coatings
Water
Composite materials
Experiments

ASJC Scopus subject areas

  • General

Cite this

Lipatov, A., Lu, H., Alhabeb, M., Anasori, B., Gruverman, A., Gogotsi, Y., & Sinitskii, A. (2018). Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Science Advances, 4(6), [eaat0491]. https://doi.org/10.1126/sciadv.aat0491

Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. / Lipatov, Alexey; Lu, Haidong; Alhabeb, Mohamed; Anasori, Babak; Gruverman, Alexei; Gogotsi, Yury; Sinitskii, Alexander.

In: Science Advances, Vol. 4, No. 6, eaat0491, 15.06.2018.

Research output: Contribution to journalArticle

Lipatov, A, Lu, H, Alhabeb, M, Anasori, B, Gruverman, A, Gogotsi, Y & Sinitskii, A 2018, 'Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers', Science Advances, vol. 4, no. 6, eaat0491. https://doi.org/10.1126/sciadv.aat0491
Lipatov A, Lu H, Alhabeb M, Anasori B, Gruverman A, Gogotsi Y et al. Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Science Advances. 2018 Jun 15;4(6). eaat0491. https://doi.org/10.1126/sciadv.aat0491
Lipatov, Alexey ; Lu, Haidong ; Alhabeb, Mohamed ; Anasori, Babak ; Gruverman, Alexei ; Gogotsi, Yury ; Sinitskii, Alexander. / Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. In: Science Advances. 2018 ; Vol. 4, No. 6.
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