Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond

Zhenshan Jia, Qianyan Zhang, Yuliang Li, Liangbing Gan, Bo Zheng, Gu Yuan, Shiwei Zhang, Daoben Zhu

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The bromine atom in a fullerene-mixed peroxide derivative is replaced by an alkoxyl group under visible light irradiation or in the presence of silver salt. Homolytic or heterolytic cleavage of the C60-Br bond is proposed to explain the mechanism. The presence of oxygen is also a key factor in the photolysis reaction.

Original languageEnglish (US)
Pages (from-to)9120-9123
Number of pages4
JournalTetrahedron
Volume63
Issue number37
DOIs
StatePublished - Sep 10 2007

Fingerprint

Fullerenes
Bromine
Photolysis
Peroxides
Silver
Salts
Irradiation
Oxygen
Derivatives
Light
Atoms

Keywords

  • Alkoxylation
  • Fullerene
  • Halogenation
  • Heterolysis
  • Homolysis

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond. / Jia, Zhenshan; Zhang, Qianyan; Li, Yuliang; Gan, Liangbing; Zheng, Bo; Yuan, Gu; Zhang, Shiwei; Zhu, Daoben.

In: Tetrahedron, Vol. 63, No. 37, 10.09.2007, p. 9120-9123.

Research output: Contribution to journalArticle

Jia, Zhenshan ; Zhang, Qianyan ; Li, Yuliang ; Gan, Liangbing ; Zheng, Bo ; Yuan, Gu ; Zhang, Shiwei ; Zhu, Daoben. / Efficient conversion of bromofullerene to alkoxyfullerenes through either homolytic or heterolytic cleavage of C60-Br bond. In: Tetrahedron. 2007 ; Vol. 63, No. 37. pp. 9120-9123.
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AU - Zheng, Bo

AU - Yuan, Gu

AU - Zhang, Shiwei

AU - Zhu, Daoben

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