Direct measurement of the hydration state of ambient aerosol populations

Joshua L. Santarpia, Runjun Li, Don R. Collins

Research output: Contribution to journalArticle

41 Scopus citations

Abstract

During the summer of 2002 a modified tandem differential mobility analyzer (TDMA) was used to examine the size-resolved hydration state of the ambient aerosol in southeast Texas. Throughout the study period the sampled aerosol had been exposed to a relative humidity (RH) greater than 80% before or soon after sunrise, while the ambient RH during sampling ranged from about 50 to 70%. To examine any possible size dependence, while also maximizing time resolution, 160 and 320 nm particles were analyzed. To assist in the interpretation of these data, a second, RH-scanning, TDMA was concurrently operated to directly characterize the deliquescence and crystallization properties of the aerosol. The hygroscopic growth of the more hygroscopic population of 160 and 320 nm particles was below that predicted for pure inorganics such as ammonium sulfate, suggesting the sampled particles were composed of mixtures of soluble and insoluble compounds. Although there were slight variations in the measured properties over the course of the study, those particles that were observed to exhibit hygroscopic growth hysteresis were almost always present as metastable aqueous solutions.

Original languageEnglish (US)
Pages (from-to)D18209 1-16
JournalJournal of Geophysical Research Atmospheres
Volume109
Issue number18
DOIs
StatePublished - Sep 27 2004

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Keywords

  • Crystallization
  • Deliquescence
  • Hygroscopic

ASJC Scopus subject areas

  • Geophysics
  • Forestry
  • Oceanography
  • Aquatic Science
  • Ecology
  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth-Surface Processes
  • Atmospheric Science
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Palaeontology

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