Determination of yttrium in titanium alloys using laser-induced breakdown spectroscopy assisted with laser-induced fluorescence

M. Shen, C. M. Li, D. Na, Z. Q. Hao, X. Y. Li, L. B. Guo, Yongfeng Lu, X. Y. Zeng

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Determining the concentration of material enhancing elements is one of the key issues for ensuring the quality and performance of titanium alloy products. Traditional methods used for determining these elements lack the ability of fast and in situ analysis, and have slowed the research and development of these products. In this work, the determination of yttrium in titanium alloys using laser-induced breakdown spectroscopy assisted with laser-induced fluorescence (LIBS-LIF) has been investigated. With the selective enhancement of the characteristic lines of yttrium under optimized parameters, analytical performance was overwhelmingly improved with a limit of detection (LoD) of 0.3 ppm, a coefficient of determination (R2) of 0.995, and a root mean square error of cross validation (RMSECV) of 12 ppm. The results demonstrate that LIBS-LIF is an effective method for the quantification of yttrium in titanium alloys, and the procedure itself works as a great complement to LIBS based analytical chemistry.

Original languageEnglish (US)
Pages (from-to)658-662
Number of pages5
JournalJournal of Analytical Atomic Spectrometry
Volume33
Issue number4
DOIs
StatePublished - Apr 1 2018
Externally publishedYes

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Laser induced breakdown spectroscopy
Yttrium
Titanium alloys
Fluorescence
Lasers
Mean square error
Chemical analysis

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

Determination of yttrium in titanium alloys using laser-induced breakdown spectroscopy assisted with laser-induced fluorescence. / Shen, M.; Li, C. M.; Na, D.; Hao, Z. Q.; Li, X. Y.; Guo, L. B.; Lu, Yongfeng; Zeng, X. Y.

In: Journal of Analytical Atomic Spectrometry, Vol. 33, No. 4, 01.04.2018, p. 658-662.

Research output: Contribution to journalArticle

Shen, M. ; Li, C. M. ; Na, D. ; Hao, Z. Q. ; Li, X. Y. ; Guo, L. B. ; Lu, Yongfeng ; Zeng, X. Y. / Determination of yttrium in titanium alloys using laser-induced breakdown spectroscopy assisted with laser-induced fluorescence. In: Journal of Analytical Atomic Spectrometry. 2018 ; Vol. 33, No. 4. pp. 658-662.
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