Detecting weak interactions between Au- and gas molecules: A photoelectron spectroscopic and Ab initio study

Yi Gao, Wei Huang, Jeffrey Woodford, Lai Sheng Wang, Cheng Zeng Xiao

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

(Figure Presented) We show that anion photoelectron spectroscopy can be a very sensitive probe for weak intermolecular interactions between gold anion and a noble-gas atom or other nonreactive molecule. High-level ab initio calculations support the measured trend of relatively weak intermolecular interactions among various gold anion?atom complexes. The interaction between Au? and H2O is much stronger, comparable to a strong hydrogen bond. The interaction between Au? and O2 is weaker than that between Au? and a noble-gas atom (Ar, Kr, or Xe).

Original languageEnglish (US)
Pages (from-to)9484-9485
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number27
DOIs
StatePublished - Jul 15 2009

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Photoelectrons
Anions
Noble Gases
Negative ions
Gases
Inert gases
Gold
Atoms
Molecules
Photoelectron Spectroscopy
Photoelectron spectroscopy
Hydrogen
Hydrogen bonds

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Detecting weak interactions between Au- and gas molecules : A photoelectron spectroscopic and Ab initio study. / Gao, Yi; Huang, Wei; Woodford, Jeffrey; Wang, Lai Sheng; Xiao, Cheng Zeng.

In: Journal of the American Chemical Society, Vol. 131, No. 27, 15.07.2009, p. 9484-9485.

Research output: Contribution to journalArticle

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