Crystal structures and luminescent properties of the lanthanide picrate complexes with an amide-type tripodal ligand

Yu Tang, Kuan Zhen Tang, Jian Zhang, Cheng Yong Su, Wei Sheng Liu, Min Yu Tan

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Solid complexes of lanthanide picrates with a new amide type tripodal ligand, 2,2′,2″-nitrilotris-(N-phenylmethyl)-acetamide (L) have been prepared. The X-ray single-crystal diffraction analysis indicates that the ML2 type complexes [PrL2(Pic)](Pic)2 and [NdL2(Pic)](Pic)2 are isomorphous. And the ML2 complex units are hydrogen bonded to give infinite one-dimensional zigzag supramolecular chains which are further linked by the interchain hydrogen bonds and π-π interactions of the picrate groups to form two-dimensional layer. The luminescent property of the Eu (III) complex is described.

Original languageEnglish (US)
Pages (from-to)1018-1021
Number of pages4
JournalInorganic Chemistry Communications
Volume8
Issue number11
DOIs
StatePublished - Nov 1 2005

Fingerprint

Picrates
picrates
Lanthanoid Series Elements
Rare earth elements
Amides
amides
Hydrogen
Hydrogen bonds
Diffraction
Crystal structure
Ligands
Single crystals
X rays
ligands
crystal structure
X-Rays
hydrogen bonds
single crystals
hydrogen
diffraction

Keywords

  • Crystal structure
  • Lanthanide picrate complexes
  • Luminescent properties
  • Tripodal ligand

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Crystal structures and luminescent properties of the lanthanide picrate complexes with an amide-type tripodal ligand. / Tang, Yu; Tang, Kuan Zhen; Zhang, Jian; Su, Cheng Yong; Liu, Wei Sheng; Tan, Min Yu.

In: Inorganic Chemistry Communications, Vol. 8, No. 11, 01.11.2005, p. 1018-1021.

Research output: Contribution to journalArticle

Tang, Yu ; Tang, Kuan Zhen ; Zhang, Jian ; Su, Cheng Yong ; Liu, Wei Sheng ; Tan, Min Yu. / Crystal structures and luminescent properties of the lanthanide picrate complexes with an amide-type tripodal ligand. In: Inorganic Chemistry Communications. 2005 ; Vol. 8, No. 11. pp. 1018-1021.
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