Calix[4]arene nitroxide tetraradical and octaradical

Arnon Olankitwanit, Velavan Kathirvelu, Suchada Rajca, Gareth R. Eaton, Sandra S. Eaton, Andrzej Rajca

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

1,3-Alternate calix[4]arene with para-phenylene spacers connecting nitroxide monoradicals and high-spin (S = 1) diradicals provides tetraradical and octaradical scaffolds that possess conformations with slow electron spin relaxation rates (1/T1). Such scaffolds may facilitate tuning of relaxation rates that are more favorable for MRI or DNP applications.

Original languageEnglish (US)
Pages (from-to)6443-6445
Number of pages3
JournalChemical Communications
Volume47
Issue number22
DOIs
StatePublished - Jun 14 2011

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Olankitwanit, A., Kathirvelu, V., Rajca, S., Eaton, G. R., Eaton, S. S., & Rajca, A. (2011). Calix[4]arene nitroxide tetraradical and octaradical. Chemical Communications, 47(22), 6443-6445. https://doi.org/10.1039/c1cc11172h