Broadly applicable synthesis of 1,2,4,5-tetraoxanes

Prasanta Ghorai, Patrick H. Dussault

Research output: Contribution to journalArticle

61 Citations (Scopus)

Abstract

Re 2O 7 is a mild and efficient catalyst for the high-yielding condensation of 1,1-dihydroperoxides with ketones or aldehydes to form 1,2,4,5-tetraoxanes, including targets not easily prepared via existing methodology. When applied in tandem with a recently reported Re(VII)-catalyzed synthesis of 1,1-dihydroperoxides, the reaction provides a high-yielding one-pot conversion of ketones or aldehydes to tetraoxanes.

Original languageEnglish (US)
Pages (from-to)213-216
Number of pages4
JournalOrganic Letters
Volume11
Issue number1
DOIs
StatePublished - Jan 1 2009

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Tetraoxanes
Ketones
aldehydes
Aldehydes
ketones
synthesis
Condensation
condensation
methodology
catalysts
Catalysts

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Broadly applicable synthesis of 1,2,4,5-tetraoxanes. / Ghorai, Prasanta; Dussault, Patrick H.

In: Organic Letters, Vol. 11, No. 1, 01.01.2009, p. 213-216.

Research output: Contribution to journalArticle

Ghorai, Prasanta ; Dussault, Patrick H. / Broadly applicable synthesis of 1,2,4,5-tetraoxanes. In: Organic Letters. 2009 ; Vol. 11, No. 1. pp. 213-216.
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