Benign Fabrication of Fully Stereocomplex Polylactide with High Molecular Weights via a Thermally Induced Technique

Yue Chang, Zhize Chen, Yiqi Yang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A reproducible and environmentally friendly method for the preparation of high molecular-weight stereocomplex polylactide (HMW SCPLA) is achieved. Poly(l-lactide) and poly(d-lactide) were simply dissolved in an environmentally friendly solvent, dibasic ester (DBE), at 110 °C. Then, the two solutions were mixed and cooled to room temperature, and the HMW SCPLA spontaneously precipitated in the form of fine powder consequently. The presence of the DBE reduced the reaction temperature and improved the molecular mobility of the polymers; thus, the degradation problems and the molecular diffusion issue in the process of the formation of the stereocomplex could be overcome. The relationship among the concentration of the mixture, degree of stereo-complexation, and thermal properties of SCPLA powders was also established. Moreover, porous membrane and film SCPLA material with good thermal properties were also obtained using this thermally induced technique. This method could be a good approach to expand the SCPLA applications.

Original languageEnglish (US)
Pages (from-to)7979-7984
Number of pages6
JournalACS Omega
Volume3
Issue number7
DOIs
StatePublished - Jul 31 2018

Fingerprint

Esters
Thermodynamic properties
Molecular weight
Powders
Fabrication
Complexation
Membranes
Degradation
Temperature
Polymers
poly(lactide)
dilactide

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Benign Fabrication of Fully Stereocomplex Polylactide with High Molecular Weights via a Thermally Induced Technique. / Chang, Yue; Chen, Zhize; Yang, Yiqi.

In: ACS Omega, Vol. 3, No. 7, 31.07.2018, p. 7979-7984.

Research output: Contribution to journalArticle

@article{2f0ca01f6e184a6c882f8edb635a5a94,
title = "Benign Fabrication of Fully Stereocomplex Polylactide with High Molecular Weights via a Thermally Induced Technique",
abstract = "A reproducible and environmentally friendly method for the preparation of high molecular-weight stereocomplex polylactide (HMW SCPLA) is achieved. Poly(l-lactide) and poly(d-lactide) were simply dissolved in an environmentally friendly solvent, dibasic ester (DBE), at 110 °C. Then, the two solutions were mixed and cooled to room temperature, and the HMW SCPLA spontaneously precipitated in the form of fine powder consequently. The presence of the DBE reduced the reaction temperature and improved the molecular mobility of the polymers; thus, the degradation problems and the molecular diffusion issue in the process of the formation of the stereocomplex could be overcome. The relationship among the concentration of the mixture, degree of stereo-complexation, and thermal properties of SCPLA powders was also established. Moreover, porous membrane and film SCPLA material with good thermal properties were also obtained using this thermally induced technique. This method could be a good approach to expand the SCPLA applications.",
author = "Yue Chang and Zhize Chen and Yiqi Yang",
year = "2018",
month = "7",
day = "31",
doi = "10.1021/acsomega.8b00902",
language = "English (US)",
volume = "3",
pages = "7979--7984",
journal = "ACS Omega",
issn = "2470-1343",
publisher = "American Chemical Society",
number = "7",

}

TY - JOUR

T1 - Benign Fabrication of Fully Stereocomplex Polylactide with High Molecular Weights via a Thermally Induced Technique

AU - Chang, Yue

AU - Chen, Zhize

AU - Yang, Yiqi

PY - 2018/7/31

Y1 - 2018/7/31

N2 - A reproducible and environmentally friendly method for the preparation of high molecular-weight stereocomplex polylactide (HMW SCPLA) is achieved. Poly(l-lactide) and poly(d-lactide) were simply dissolved in an environmentally friendly solvent, dibasic ester (DBE), at 110 °C. Then, the two solutions were mixed and cooled to room temperature, and the HMW SCPLA spontaneously precipitated in the form of fine powder consequently. The presence of the DBE reduced the reaction temperature and improved the molecular mobility of the polymers; thus, the degradation problems and the molecular diffusion issue in the process of the formation of the stereocomplex could be overcome. The relationship among the concentration of the mixture, degree of stereo-complexation, and thermal properties of SCPLA powders was also established. Moreover, porous membrane and film SCPLA material with good thermal properties were also obtained using this thermally induced technique. This method could be a good approach to expand the SCPLA applications.

AB - A reproducible and environmentally friendly method for the preparation of high molecular-weight stereocomplex polylactide (HMW SCPLA) is achieved. Poly(l-lactide) and poly(d-lactide) were simply dissolved in an environmentally friendly solvent, dibasic ester (DBE), at 110 °C. Then, the two solutions were mixed and cooled to room temperature, and the HMW SCPLA spontaneously precipitated in the form of fine powder consequently. The presence of the DBE reduced the reaction temperature and improved the molecular mobility of the polymers; thus, the degradation problems and the molecular diffusion issue in the process of the formation of the stereocomplex could be overcome. The relationship among the concentration of the mixture, degree of stereo-complexation, and thermal properties of SCPLA powders was also established. Moreover, porous membrane and film SCPLA material with good thermal properties were also obtained using this thermally induced technique. This method could be a good approach to expand the SCPLA applications.

UR - http://www.scopus.com/inward/record.url?scp=85050398272&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85050398272&partnerID=8YFLogxK

U2 - 10.1021/acsomega.8b00902

DO - 10.1021/acsomega.8b00902

M3 - Article

VL - 3

SP - 7979

EP - 7984

JO - ACS Omega

JF - ACS Omega

SN - 2470-1343

IS - 7

ER -