Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

Tahir H. Tahirov, Tian Huey Lu, Fen Ling Liao, Sue Lein Wang, Bor Hann Chen, Ta Yung Chi, Chung Sun Chung

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

Original languageEnglish (US)
Pages (from-to)2687-2689
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number11
DOIs
StatePublished - Nov 15 1996

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Copper
Ligands
Conformations
copper
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atoms
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ligands
rings
configurations
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ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate. / Tahirov, Tahir H.; Lu, Tian Huey; Liao, Fen Ling; Wang, Sue Lein; Chen, Bor Hann; Chi, Ta Yung; Chung, Chung Sun.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 11, 15.11.1996, p. 2687-2689.

Research output: Contribution to journalArticle

Tahirov, Tahir H. ; Lu, Tian Huey ; Liao, Fen Ling ; Wang, Sue Lein ; Chen, Bor Hann ; Chi, Ta Yung ; Chung, Chung Sun. / Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate. In: Acta Crystallographica Section C: Crystal Structure Communications. 1996 ; Vol. 52, No. 11. pp. 2687-2689.
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abstract = "The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.",
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T1 - Aqua(1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane-N,N′, N″,N‴)copper(II) Diperchlorate

AU - Tahirov, Tahir H.

AU - Lu, Tian Huey

AU - Liao, Fen Ling

AU - Wang, Sue Lein

AU - Chen, Bor Hann

AU - Chi, Ta Yung

AU - Chung, Chung Sun

PY - 1996/11/15

Y1 - 1996/11/15

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AB - The CuII ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO 4)2, is five-coordinate in a distorted square-pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR, 11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

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