A novel sol-gel route to pinhole-free iron sulfide thin films

S. Kment, H. Kmentova, A. Sarkar, R. J. Soukup, N. J. Ianno, J. Krysa, Z. Hubicka, J. Olejnicek, C. L. Exstrom, S. A. Darveau

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The general purpose of the study is to fabricate and improve upon FeS 2 thin films which can be used as the photon absorber layer for a heterojunction or homojunction solar cell. This work deals with the preparation of the pyrite by an unconventional sol-gel approach. Thin pyrite films were prepared by sulfurizing the iron oxide films previously deposited through the sol-gel method using iron (III) chloride as a precursor. The structural, morphological, electronic and optical properties of the deposited films were determined using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, Auger electron spectroscopy (AES), UV-Vis absorption spectroscopy, Hall effect and profilometry. The effects of annealing and sulfurization temperatures were studied. The work was also devoted to the research of sodium diffusion from the substrate due to the thermal treatment and its affect on the pyrite films functionality.

Original languageEnglish (US)
Title of host publicationProgram - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011
Pages1287-1291
Number of pages5
DOIs
StatePublished - Dec 1 2011
Event37th IEEE Photovoltaic Specialists Conference, PVSC 2011 - Seattle, WA, United States
Duration: Jun 19 2011Jun 24 2011

Publication series

NameConference Record of the IEEE Photovoltaic Specialists Conference
ISSN (Print)0160-8371

Other

Other37th IEEE Photovoltaic Specialists Conference, PVSC 2011
CountryUnited States
CitySeattle, WA
Period6/19/116/24/11

Fingerprint

Pyrites
Sol-gels
Iron
Thin films
Profilometry
Hall effect
Auger electron spectroscopy
Ultraviolet spectroscopy
Absorption spectroscopy
Iron oxides
Electronic properties
Sol-gel process
Oxide films
Raman spectroscopy
Heterojunctions
Structural properties
Solar cells
Photons
Optical properties
Heat treatment

ASJC Scopus subject areas

  • Control and Systems Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

Cite this

Kment, S., Kmentova, H., Sarkar, A., Soukup, R. J., Ianno, N. J., Krysa, J., ... Darveau, S. A. (2011). A novel sol-gel route to pinhole-free iron sulfide thin films. In Program - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011 (pp. 1287-1291). [6186193] (Conference Record of the IEEE Photovoltaic Specialists Conference). https://doi.org/10.1109/PVSC.2011.6186193

A novel sol-gel route to pinhole-free iron sulfide thin films. / Kment, S.; Kmentova, H.; Sarkar, A.; Soukup, R. J.; Ianno, N. J.; Krysa, J.; Hubicka, Z.; Olejnicek, J.; Exstrom, C. L.; Darveau, S. A.

Program - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011. 2011. p. 1287-1291 6186193 (Conference Record of the IEEE Photovoltaic Specialists Conference).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kment, S, Kmentova, H, Sarkar, A, Soukup, RJ, Ianno, NJ, Krysa, J, Hubicka, Z, Olejnicek, J, Exstrom, CL & Darveau, SA 2011, A novel sol-gel route to pinhole-free iron sulfide thin films. in Program - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011., 6186193, Conference Record of the IEEE Photovoltaic Specialists Conference, pp. 1287-1291, 37th IEEE Photovoltaic Specialists Conference, PVSC 2011, Seattle, WA, United States, 6/19/11. https://doi.org/10.1109/PVSC.2011.6186193
Kment S, Kmentova H, Sarkar A, Soukup RJ, Ianno NJ, Krysa J et al. A novel sol-gel route to pinhole-free iron sulfide thin films. In Program - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011. 2011. p. 1287-1291. 6186193. (Conference Record of the IEEE Photovoltaic Specialists Conference). https://doi.org/10.1109/PVSC.2011.6186193
Kment, S. ; Kmentova, H. ; Sarkar, A. ; Soukup, R. J. ; Ianno, N. J. ; Krysa, J. ; Hubicka, Z. ; Olejnicek, J. ; Exstrom, C. L. ; Darveau, S. A. / A novel sol-gel route to pinhole-free iron sulfide thin films. Program - 37th IEEE Photovoltaic Specialists Conference, PVSC 2011. 2011. pp. 1287-1291 (Conference Record of the IEEE Photovoltaic Specialists Conference).
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