A New Synthon for Optically Active Diene Hydroperoxides

Patrick Dussault, In Quen Lee, Scott Kreifels

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The olefination of an enzymatically derived γ-peroxy-α,β-unsaturated aldehyde (1) allows the synthesis of optically active diene hydroperoxides in high enantiomeric excess. The application of this method to the synthesis of 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid methyl ester is presented.

Original languageEnglish (US)
Pages (from-to)4087-4089
Number of pages3
JournalJournal of Organic Chemistry
Volume56
Issue number13
DOIs
StatePublished - Jun 1 1991

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Hydrogen Peroxide
Aldehydes
Esters
octadecadienoic acid

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

A New Synthon for Optically Active Diene Hydroperoxides. / Dussault, Patrick; Lee, In Quen; Kreifels, Scott.

In: Journal of Organic Chemistry, Vol. 56, No. 13, 01.06.1991, p. 4087-4089.

Research output: Contribution to journalArticle

Dussault, Patrick ; Lee, In Quen ; Kreifels, Scott. / A New Synthon for Optically Active Diene Hydroperoxides. In: Journal of Organic Chemistry. 1991 ; Vol. 56, No. 13. pp. 4087-4089.
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