2-Chlorophenyl 3-nitrobenzene-sulfonate and 2,4-dichlorophenyl 3-nitrobenzenesulfonate: Supramolecular aggregation through C-H⋯O, π-π and van der Waals interactions

Nagarajan Vembu, Maruthai Nallu, Semih Durmus, Mathew Pazner, Jered Garrison, Wiley J. Youngs

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Abstract

The molecular and crystal structures of 2-chlorophenyl 3-nitrobenzene-sulfonate and 2,4-dichlorophenyl 3-nitrobenzenesulfonate were analyzed. It was found that weak C-H···O interactions generated S(5), S(6) and R22(7) rings in the compounds. The supramolecular aggregation was also found to be completed by the presence of π-π interactions and intermolecular van der Walls short contacts. The analysis showed that the antiperiplanar/anticlinical orientation relieved the molecule from the steric strain, thereby facilitating the adoption of a coplanar orientation.

Original languageEnglish (US)
Pages (from-to)o65-o68
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume60
Issue number1
DOIs
StatePublished - Jan 1 2004

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nitrobenzenes
sulfonates
Molecular Structure
Molecular structure
Agglomeration
Crystal structure
Molecules
molecular structure
interactions
crystal structure
rings
molecules
nitrobenzene

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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2-Chlorophenyl 3-nitrobenzene-sulfonate and 2,4-dichlorophenyl 3-nitrobenzenesulfonate : Supramolecular aggregation through C-H⋯O, π-π and van der Waals interactions. / Vembu, Nagarajan; Nallu, Maruthai; Durmus, Semih; Pazner, Mathew; Garrison, Jered; Youngs, Wiley J.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 60, No. 1, 01.01.2004, p. o65-o68.

Research output: Contribution to journalArticle

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